期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 78, 页码 14628-14631出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc06044c
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资金
- China Scholarship Council
An N-heterocyclic carbene catalyzed activation of alpha,beta-unsaturated N-acyltriazoles is described. The in situ generated alpha,beta-unsaturated acylazolium intermediates allowed an enantioselective formal [3+3] cycloaddition with 1,3-dicarbonyl compounds. The resulting dihydro-pyranones are formed in good to excellent yields and with high enantioselectivities.
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