期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 87, 页码 15819-15822出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05371d
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资金
- NSFC [21171159]
- Innovative Research Groups [20921002]
A slow reaction between Nd3+ and piperazine-1,4-dicarbodithiolate disodium (Na-2(pipzdtc)) affords a three dimensional (3D) anionic [Nd(pipzdtc)(2)](n)(n-) framework with a dia net. The encapsulated disordered guest molecules could be partially exchanged by Ni2+ accompanied by the quenching of the typical NIR luminescence of Nd3+ ions.
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