期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 16, 页码 3316-3319出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07876d
关键词
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资金
- EPSRC [EP/H025839/1]
- Engineering and Physical Sciences Research Council [EP/H025839/1] Funding Source: researchfish
A flexible, modular ynamide synthesis is reported that uses trichloroethene as an inexpensive two carbon synthon. A wide range of amides and electrophiles can be converted to the corresponding ynamides, importantly including acyclic carbamates, hindered amides, and aryl amides. This method thus overcomes many of the limitations of other approaches to this useful functionality.
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