期刊
MACROMOLECULES
卷 49, 期 12, 页码 4473-4479出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.6b00101
关键词
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资金
- National Science Foundation [CHE-1302043]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1660373] Funding Source: National Science Foundation
Functional polystyrenes and polyacrylamides, containing combinations of fluorosulfate, aromatic silyl ether, and azide side chains, were used as scaffolds to demonstrate the postpolymerization modification capabilities of sulfur(VI) fluoride exchange (SuFEx) and CuAAC chemistries. Fluorescent dyes bearing appropriate functional groups were sequentially attached to the backbone of the copolymers, quantitatively and selectively addressing their reactive partners. This combined SuFEx and CuAAC approach proved to be robust and versatile, allowing for a rare accomplishment: triple orthogonal functionalization of a copolymer under essentially ambient conditions without protecting groups.
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