期刊
MACROMOLECULES
卷 49, 期 19, 页码 7350-7358出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.6b00889
关键词
-
资金
- DOE Office of Science [DE-AC02-98CH10886]
- NSF [DMR-1534910]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1534910] Funding Source: National Science Foundation
Limited long-range ordering and the presence of both hard and soft segments can cause substantial difficulties for structure determination in urethane elastomers. Here, the structuring has been investigated for a series of thermoplastic polyurethanes composed of 4,4'-methylene diphenyl diisocyanate and 1,4-butanediol. We utilize pair distribution function analysis of X-ray total scattering measurements to directly access the local structure and quantify the degree of ordering, showing that the structure varies significantly over the range of different component ratios investigated. A simple method is demonstrated for evaluating the viability of various structure candidates for the hard segment. The nature of the molecular conformations and packing is verified, allowing both ordered and disordered components to be quantified through structural modeling.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据