Nickel-iron catalyst for decomposition of methane to hydrogen and filamentous carbon: Effect of calcination and reaction temperatures

Nickel-ferrite Ni-Fe (molar ratio 1:2) were synthesised and calcined at different temperatures. The catalytic performances of Ni-Fe for methane decomposition and production of hydrogen and carbon nanostructures were evaluated at various calcination (350-800 degrees C) and reaction temperatures (700-800 degrees C). Fresh and spent catalysts were characterized using scanning electron microscopy (SEM), BET surface area, X-ray diffraction (XRD), TGA and Raman spectroscopy. XRD results revealed the formation of highly crystalline NiFe2O4 in calcined samples, while Ni-Fe alloys were observed in the spent catalysts. The NiFe2O4 catalyst has a mesoporous structure with monomodal pore distribution. The surface area decreased from 107.0 to 3.8 m(2)/g with increasing calcination temperature from 350 to 800 degrees C. Methane conversion, 48.50%, and hydrogen formation rate, 97.70 x 10(-5) mol H-2 g(-1) min(-1) was obtained at reaction temperature of 800 degrees C. The catalyst activity slightly improved by increasing calcination temperature. The SEM images of spent catalysts revealed the formation of some filamentous carbon over all spent catalysts except for that operated at reaction temperature of 700 degrees C. TGA studies revealed that the deposited carbon increased with increase in reaction and calcination temperatures and achieved 42.50 and 59.32 wt %, respectively. The graphitization and crystalline of the deposited carbon slightly decreases as calcination temperature increased. (c) 2022 THE AUTHORS. Published by Elsevier BV on behalf of Faculty of Engineering, Alexandria University.

Automated summary

Nickel-ferrite Ni-Fe catalysts were synthesized and calcined at different temperatures for methane decomposition and hydrogen production. The catalysts were characterized using various techniques and evaluated for their performance. The results showed the formation of crystalline NiFe2O4 in calcined samples and Ni-Fe alloys in spent catalysts. The catalysts exhibited high methane conversion and hydrogen formation rates, which slightly improved with increasing calcination temperature.