4.6 Article

Influence of a Propagating Megahertz Surface Acoustic Wave on the Pattern Deposition of Solute Mass off an Evaporating Solution

期刊

LANGMUIR
卷 32, 期 37, 页码 9611-9618

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AMER CHEMICAL SOC
DOI: 10.1021/acs.langmuir.6b01341

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  1. German Israel Science Foundation (GIF) [2336]
  2. Israel Science Foundation (ISF) [489/14]

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We study the influence of a megahertz Rayleigh surface acoustic wave (SAW), propagating in a solid substrate, on the pattern deposition of a solute mass off an evaporating solution. An experimental procedure, where a film of a solution undergoes a controlled evaporation in a chamber, shows that the SAW alters the state of the pattern deposition. Increasing the power of the SAW supports an increase in the density of the deposited patterns. Beyond threshold conditions, the deposited. patterns merge and we observe the deposition of a solid film. A simplified theory suggests that the SAW deforms the geometry of the film, which is predominantly governed-by the capillary stress. The deformation of the film taking place alongside with the evaporation of the solution increases the concentration near the pinned three phase contact line at the front of the film, which is closer to the source of the SAW, on the expense of the concentration at the rear. The increased concentration translates to the deposition of solute mass over an increased area near the front of the film, which explains the experimental observation.

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