期刊
CHEMCATCHEM
卷 7, 期 20, 页码 3322-3331出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201500545
关键词
biomass; heterogeneous catalysis; Lewis acids; tin; zeolites
资金
- Royal Society [RG140754]
- UK Catalysis Hub [EP/K014714/1]
- EPSRC [EP/I019693/1]
- University of Bologna (Italy)
- Al-Qadisiya University (Iraq)
- EPSRC [EP/I019693/1, EP/K014714/1] Funding Source: UKRI
Lewis acidic zeolites are rapidly emerging liquid-phase Lewis acid catalysts. Nevertheless, their inefficient synthesis procedure currently prohibits greater utilization and exploitation of these promising materials. Herein, we demonstrate that Sn-IV-containing zeolite beta can readily be prepared both selectively and extremely rapidly by solid-state incorporation (SSI) method. Through a combination of spectroscopic (XRD, UV/Vis, X-ray absorption, magic-angle spinning NMR, and diffuse reflectance infrared Fourier transform spectroscopy) studies, we unambiguously demonstrate that site-isolated, isomorphously substituted Sn-IV sites dominate the Sn population up to a loading of 5wt% Sn. These sites are identical to those found in conventionally prepared Sn-beta, and result in our SSI material exhibiting identical levels of intrinsic activity (that is, turnover frequency) despite the threefold increase in Sn loading, and the extremely rapid and benign nature of our preparation methodology. We also identify the presence of spectator sites, in the form of Sn-IV oligomers, at higher levels of Sn loading. The consequences of this mixed population with regards to catalysis (Meerwein-Pondorf-Verley reaction and glucose isomerization) are also identified.
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