Article
Chemistry, Physical
Xingyuan Gao, Jinglong Liang, Liqing Wu, Lixia Wu, Sibudjing Kawi
Summary: This paper provides a detailed summary of the applications of dielectric barrier discharge (DBD) plasma in catalytic CO2 hydrogenation, and discusses the design of the reactor and optimization of reaction parameters. Additionally, several mechanisms are explored and proposed solutions to existing challenges are provided.
Article
Engineering, Environmental
Baharak Sajjadi, Wei-Yin Chen
Summary: This study investigates the catalytic routes for upgrading CO2 through the Sabatier reaction using non-thermal plasma. The impacts of reactor geometry, plasma conditions, and catalyst promoters on plasma discharge and CO2 conversion are studied. The results show that the catalysts perform better in plasma discharge at lower temperatures than in thermal conversion at 400°C.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Applied
Haoran Wu, Shilong Xiong, Chang-jun Liu
Summary: The argon dielectric barrier discharge (DBD) plasma decomposition of Zr(OH)4 can be used to prepare amorphous ZrO2, which acts as a support for the active catalyst In2O3/am-ZrO2 for CO2 hydrogenation to methanol. The thermal treatment of DBD generated am-ZrO2 further enhances the activity of the catalyst.
Article
Chemistry, Multidisciplinary
Nitesh Joshi, L. Sivachandiran
Summary: The study found that binary mixed metal oxides of NiO-Fe2O3 are more active than pure metal oxides, but increased NiO mixing leads to particle agglomeration. Plasma coupled with the catalyst significantly enhances CO2 conversion and CH3OH yield, showing a 5.8-fold improvement with 10NF at 200 degrees C compared to thermal catalysis.
Article
Energy & Fuels
Tingting Wang, Meng Su, Qiang Wang, Zhenhua Li
Summary: The effects of the incorporation amount of Ca on the formation of C-2-C-4 in the hydrogenation of CO2-to-light hydrocarbons in a hybrid dielectric barrier discharge-perovskite catalysis system were studied. A series of La1-xCaxNiO3 catalysts were prepared and characterized. The La-0.7-Ca-0.3-Ni catalyst showed the best performance, achieving CO2 conversion as high as 83.1% with selectivity of C-2-C-4 as 11.8%.
Review
Engineering, Chemical
Sana Ullah, Yuan Gao, Liguang Dou, Yadi Liu, Tao Shao, Yunxia Yang, Anthony B. Murphy
Summary: Plasma technology shows promise for gas conversion applications, with the potential to operate using intermittent renewable electricity. This article provides an overview of different types of plasma reactors and their characteristics, discusses current research on CO2 and N2 conversion, and addresses the challenges for further improvement.
PLASMA CHEMISTRY AND PLASMA PROCESSING
(2023)
Article
Engineering, Environmental
Ju Li, Shengjie Zhu, Ke Lu, Cunhua Ma, Dezheng Yang, Feng Yu
Summary: This study utilized grinding balls made of a mixture of ZrO2 and CeO2 as packing material to achieve higher CO2 conversion and energy efficiency. By investigating the effects of discharge power, feed flow rate, packing length, circulating water temperature, and particle size, the researchers were able to understand the performance of the packing material better. The mixture catalyst may have a synergistic effect and outperforms the materials composed of a single substance.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Environmental
Baowei Wang, Xiaoyan Li, Xiaoxi Wang, Bo Zhang
Summary: The study indicates that using filled dielectric materials can significantly improve the conversion rate and energy efficiency of CO2 decomposition technology, with the filled MgO reactor showing the highest performance.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Energy & Fuels
Meng Su, Xin Li, Ning Zhao, Niamat Ullah, Zhenhua Li
Summary: This study investigates the influence of A-site substitution on the catalytic performance of lanthanum nickel perovskite-type catalysts. The results show that A-site substitution can improve CO2 conversion and C2-4 selectivity, with La0.8Ca0.2NiO3 +/-delta catalyst exhibiting superior performance. The excellent performance can be attributed to the formation of smaller Ni particle size and sufficient oxygen vacancies.
Article
Engineering, Electrical & Electronic
Kaiyue Wu, Jingnan Liu, Jiacun Wu, Mo Chen, Junxia Ran, Xuexia Pang, Pengying Jia, Xuechen Li, Chenhua Ren
Summary: This article reports a double-mode argon planar plume, which operates in the streamer mode and transits to the filamentary mode. Discharge characteristics and plasma parameters are compared for the two modes, showing that the streamer mode and the filamentary mode correspond to pulsed and humped discharges respectively. Fast photography reveals that the streamer-mode plume is composed of stochastically branching streamers, while the filamentary-mode plume results from a series of moving filaments similar to those in barrier discharge. The filamentary mode has lower excited electron temperature and vibrational temperature, whereas higher electron density and gas temperature, and it achieves better hydrophilicity of polyethylene terephthalate surface.
Article
Engineering, Chemical
Zhengkun Liu, Wanglin Zhou, Yaqiong Xie, Feng Liu, Zhi Fang, Guangru Zhang, Wanqin Jin
Summary: A breakthrough strategy that uses plasma technology to enhance CO2 splitting in membrane reactors shows promise in eliminating the need for traditional catalysts and achieving energy-efficient and sustainable conversion processes.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Engineering, Environmental
Sirui Li, Michele Ongis, Giampaolo Manzolini, Fausto Gallucci
Summary: Plasma-based CO2 capture and splitting have been successfully achieved in this study, which can be instantly initiated after the ignition of plasma and stopped when the plasma is turned off. A certain amount of CO was produced during the plasma treatment, with an average conversion rate of 41.14% of CO2. The potential application of this technology in syngas production and CO2 emission reduction from power plants has been discussed based on its technological advantages.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Danhua Mei, Peng Zhang, Gehui Duan, Shiyun Liu, Ying Zhou, Zhi Fang, Xin Tu
Summary: The reforming of CH4 with CO2 using nanosecond pulsed dielectric barrier discharge (DBD) plasma shows promising results in enhancing gas conversion, but at the expense of energy efficiency. Increasing applied voltage and discharge length can enhance gas conversion, but decrease energy efficiency.
JOURNAL OF CO2 UTILIZATION
(2022)
Article
Green & Sustainable Science & Technology
Grittima Kongprawes, Doonyapong Wongsawaeng, Peter Hosemann, Kanokwan Ngaosuwan, Worapon Kiatkittipong, Suttichai Assabumrungrat
Summary: Catalytic-free parallel-plate-type dielectric barrier discharge (DBD) plasma was used to hydrogenate palm oil using glycerol as a hydrogen donor, resulting in enhanced oxidation stability of hydrogenated fatty acid methyl ester (H-FAME). Optimal reaction conditions were determined, and it was found that plasma effectively extracted hydrogen radicals from glycerol and reacted with C-C bonds. The hydrogenated palm oil was then converted into HFAME via base-catalyzed transesterification. The developed plasma hydrogenation process adds value to waste glycerol and provides alternative hydrogen sources, while also being environmentally friendly.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Engineering, Chemical
Wei Guo, Huanhao Chen
Summary: Nonthermal plasma (NTP)-assisted CO2 methanation is a technique that activates and converts CO2 molecules under ambient conditions, reducing CO2 emissions and utilizing renewable energy. In this study, a Ni catalyst supported on CeO2 with yttrium as the promoter was synthesized for efficient NTP catalytic CO2 methanation. The catalyst showed high energy conversion efficiency and excellent short-term stability.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)