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Construction of MOFs-based nanocomposite membranes for emerging organic contaminants abatement in water

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HIGHER EDUCATION PRESS
DOI: 10.1007/s11783-023-1689-x

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Emerging organic contaminants; Metal organic frameworks; Synthesis; Adsorption; Catalysis

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The presence of emerging organic contaminants in water is a major threat to its safety. Metal-organic frameworks (MOFs) have shown potential for removing these contaminants, but their practical application in wastewater treatment is still debated. This review summarizes recent studies on the use of MOFs for EOCs removal, focusing on synthesis strategies, characterization technologies, as well as their application in adsorption, separation, and catalytic degradation. Overall, MOF-based composites show promise in eliminating EOCs, with modified membranes being the most promising materials for future applications.
Presence of emerging organic contaminants (EOCs) in water is one of the major threats to water safety. In recent decades, an increasing number of studies have investigated new approaches for their effective removal. Among them, metal-organic frameworks (MOFs) have attracted increasing attention since their first development thanks to their tunable metal nodes and versatile, functional linkers. However, whether or not MOFs have a promising future for practical application in emerging contaminants-containing wastewater is debatable. This review summarizes recent studies about the removal of EOCs using MOFs-related material. The synthesis strategies of both MOF particles and composites, including thin-film nanocomposite and mixed matrix membranes, are critically reviewed, as well as various characterization technologies. The application of the MOF-based composite membranes in adsorption, separation (nanofiltration and ultrafiltration), and catalytic degradation are discussed. Overall, literature survey shows that MOFs-based composite could play a crucial role in eliminating EOCs in the future. In particular, modified membranes that realize separation and degradation might be the most promising materials for such application.

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