期刊
KOREAN JOURNAL OF CHEMICAL ENGINEERING
卷 33, 期 11, 页码 3115-3120出版社
KOREAN INSTITUTE CHEMICAL ENGINEERS
DOI: 10.1007/s11814-016-0149-8
关键词
Coke Oven Gas; Combined H2O and CO2 Reforming; Syngas; Coke; Ni-K/MgAl2O4
资金
- Korea Institute of Energy Research [B6-2423]
- C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [2015M3D3A1A01064927]
- National Research Council of Science & Technology (NST), Republic of Korea [KIER2-2] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2015M3D3A1A01064927] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A K-promoted 10Ni-(x)K/MgAl2O4 catalyst was investigated for the combined H2O and CO2 reforming (CSCR) of coke oven gas (COG) for syngas production. The 10Ni-(x)K/MgAl2O4 catalyst was prepared by co-impregnation, and the K content was varied from 0 to 5 wt%. The BET, XRD, H-2-chemisorption, H-2-TPR, and CO2-TPD were performed for determining the physicochemical properties of prepared catalysts. Except under the condition of a K/Ni=0.1 (wt%/wt%), the Ni crystal size and dispersion decreased with increasing K/Ni. The coke resistance of the catalyst was investigated under conditions of CH4: CO2: H-2: CO:N-2=1 : 1 : 2 : 0.3 : 0.3, 800 A degrees C, 5 atm. The coke formation on the used catalyst was examined by SEM and TG analysis. As compared to the 10Ni/MgAl2O4 catalyst, the Kpromoted catalyst exhibited superior activity and coke resistance, attributed to its strong interaction with Ni and support, and the improved CO2 adsorption characteristic. The 10Ni-1K/MgAl2O4 catalyst exhibited optimum activity and coke resistance with only 1wt% of K.
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