Synthesis of double-shelled periodic mesoporous organosilica nanospheres/MIL-88A-Fe composite and its elevated performance for Pb2+ removal in water

Herein, we report the synthesis of double-shelled periodic mesoporous organosilica nanospheres/MIL-88A-Fe (DSS/MIL-88A-Fe) composite through a hydrothermal method. To survey the structural and compositional features of the synthesized composite, a variety of spectroscopic and microscopic techniques, including FT-IR, XRD, BET, TEM, FE-SEM, EDX, and EDX-mapping, have been employed. A noteworthy point in this synthesis procedure is the integration of MOF with PMO to increase the adsorbent performance, such as higher specific surface area and more active sites. This combination leads to achieving a structure with an average size of 280 nm and 1.1 mu m long attributed to DSS and MOF, respectively, microporous structure and relatively large specific surface area (312.87 m(2)/g). The as-prepared composite could be used as an effective adsorbent with a high adsorption capacity (250 mg/g) and quick adsorption time (30 min) for the removal of Pb2+ from water. Importantly, DSS/MIL-88A-Fe composite revealed acceptable recycling and stability, since the performance in Pb2+ removal from water remained above 70% even after 4 consecutive cycles.

Automated summary

In this study, a double-shelled periodic mesoporous organosilica nanospheres/MIL-88A-Fe (DSS/MIL-88A-Fe) composite was synthesized through a hydrothermal method. Spectroscopic and microscopic techniques were used to characterize the structural and compositional features of the composite. The integration of MOF with PMO led to a structure with a dual-shelled morphology, microporous structure, and large specific surface area. The as-prepared composite exhibited high adsorption capacity and quick adsorption time for the removal of Pb2+ from water, along with acceptable recycling and stability.