Article
Multidisciplinary Sciences
Deshi Jin, Yilin Xiao, Dong-Bo Tan, Yang-Yang Wang, Xiaoxia Wang, Wancai Li, Wen Su, Xiaoguang Li
Summary: Supercritical fluids play a crucial role in the cycling of elements due to their low viscosity, high mobility, and high element contents. However, the chemical composition of supercritical fluids in natural rocks remains poorly understood. In this study, well-preserved primary multiphase fluid inclusions from an ultrahigh-pressure metamorphic vein in China provide direct evidence for the components of supercritical fluids in a natural system. By using 3D modeling and Raman scanning, we were able to quantitatively determine the major composition of the fluid trapped in the inclusions, indicating that these fluids represent supercritical fluids in a deep subduction zone. The high mobility of these fluids suggests significant effects on global carbon and sulfur cycling.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
(2023)
Article
Geology
Tamas Spranitz, Jose Alberto Padron-Navarta, Csaba Szabo, Abel Szabo, Marta Berkesi
Summary: The primary multiphase fluid inclusions (MFI) in the Cabo Ortegal Complex (COC) in NW Spain were found to be formed under high-pressure metamorphic conditions. The mineral assemblage of MFI consists mainly of carbonates and silicates, with proportions of nitrogen, methane and carbon dioxide. Reactions between the MFI and the host minerals resulted in carbonation and hydration reactions. This study has important implications for global nitrogen and carbon cycling, as well as the supply of nitrogen and methane in subsurface-surface environments.
JOURNAL OF METAMORPHIC GEOLOGY
(2022)
Article
Geochemistry & Geophysics
Charlotte L. DeVitre, Chelsea M. Allison, Esteban Gazel
Summary: The study proposed a new Fluid Density Calibration Apparatus (FDCA) with improved temperature measurement accuracy for CO2 densimetry in inclusions. Five new precise calibration equations were developed for different temperature and CO2 density ranges, resulting in total percent uncertainty below 5% in CO2 content calculations for samples, significantly outperforming existing literature densimeters with uncertainty higher than 10% and up to 28%.
Article
Computer Science, Interdisciplinary Applications
Austin Goodrich, Marcus Herrmann
Summary: An Eulerian method is presented to solve the vortex sheet dynamics of an interface captured by a Volume-of-Fluid (VoF) transport scheme. The methods for generating self-induced vortex sheet velocities are evaluated based on computational feasibility and solution verification properties. Grid convergence study is conducted to evaluate the convergence properties of the VoF vortex sheet method, and various hydrodynamic instabilities are presented to demonstrate its capabilities in 2D and 3D. Results are compared against prior literature and Direct Numerical Simulations.
JOURNAL OF COMPUTATIONAL PHYSICS
(2023)
Article
Mechanics
Cheng-Hsien Lee
Summary: This study developed a multiphase model with a novel evolution equation to address the issues of shear-induced volume change and pore-pressure feedback in submarine granular flows simulated using an Eulerian-Eulerian two-phase model. The evolution equation effectively describes the relaxation process of static solid pressure and shear-induced volume change, allowing the model to capture phenomena such as time delays in initiating flows and different collapse processes for differently packed columns.
JOURNAL OF FLUID MECHANICS
(2021)
Article
Computer Science, Interdisciplinary Applications
Ananthan Mohan, Gaurav Tomar
Summary: The volume of fluid (VOF) method is used for simulating two-phase flows with sharp interfaces represented by piecewise linear line segments. This study introduces analytical formulas for interface reconstruction in axisymmetric coordinates and suggests modifications to existing advection schemes in VOF for improved mass conservation accuracy in axisymmetric coordinates.
JOURNAL OF COMPUTATIONAL PHYSICS
(2021)
Article
Energy & Fuels
Ya-Hao Huang, You-Jun Tang, Mei-Jun Li, Hai-Tao Hong, Chang-Jiang Wu, Ji-Zhen Zhang, Xiao-Lin Lu, Xiao-Yong Yang
Summary: This study investigates the fluid accumulation mechanisms and reservoir properties preservation and degradation indicators in a tight gas reservoir. Different types of gas inclusions in quartz grains were studied to understand the evolution of fluid phases. Two stages of CO2 fluid accumulation were observed, with abnormally high homogenization temperatures attributed to deep hydrothermal fluid activity.
Article
Spectroscopy
Ahmet Sasmaz, Ayse Didem Kilic, Bunyamin Akgul, Bilge Sasmaz
Summary: This study investigated garnets and inclusions formed in the contact zone of Pertek granitoid and Keban marble. The main mineral assemblage observed in the skarn formation is diopside, garnet, quartz, magnetite, calcite, and pyrite. Raman spectroscopy studies revealed that the idiomorphic and semi-idiomorphic garnets are predominantly grossular, andradite, and uvarovite in the core. The chondrite-normalized REE patterns of all garnets in the study area show similar trends and are generally depleted in HREE and enriched in LREE, mainly controlled by adsorption.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Chemistry, Multidisciplinary
Eui-Sang Yu, Eui Tae Jeong, Seungha Lee, In Soo Kim, Seok Chung, Seungyeon Han, Inhee Choi, Yong-Sang Ryu
Summary: Nanoplastics in the ecosystem raise significant concerns, but their effects and quantity remain unclear. This study enables rapid collection and detection of underwater nanoplastics using new techniques.
Article
Computer Science, Interdisciplinary Applications
Van-Hoan Le, Marie-Camille Caumon, Alexandre Tarantola
Summary: Numerous calibration data linking Raman spectral parameters with PVX properties of different gases have been published, but discrepancies exist between them. This paper examines the inter-laboratory applicability of existing calibration data and provides universal calibration data and a user-friendly interface for measurements. The FRAnCIs Python interface facilitates the application of these calibrations and estimates measurement uncertainty.
COMPUTERS & GEOSCIENCES
(2021)
Article
Geochemistry & Geophysics
Kristijan Rajic, Hugues Raimbourg, Catherine Lerouge, Vincent Famin, Benoit Dubacq, Aurelien Canizares, Ida Di Carlo, Nicolas Maubec
Summary: To understand fluid-mineral reactions and fluid budget in subduction zones, rock samples from two accretionary complexes, Kodiak (Alaska) and Shimanto (Japan), were studied. Burial temperatures ranged from 230 to 350 degrees C, and pressures reached up to -3 and -4 kbars in Japanese and Alaskan complexes, respectively. Chlorite formation was observed from smectite-to-illite and illite-to-chlorite transformations at temperatures of 230-350 degrees C. Various reactions, such as pyrite oxidation and mineral dissolution, were identified. The composition of fluid inclusions indicated dilution of seawater by fresh water released during the smectite-to-illite transformation at lower temperatures, while higher temperatures showed higher salinity reflecting hydration reactions controlled by chlorite crystallization.
Article
Engineering, Chemical
E. Dianyu, Haihan Fan, Zhongfang Su, Guangtai Xu, Ruiping Zou, Aibing Yu, Shibo Kuang
Summary: This paper proposes a hydrocyclone with a tapered inlet design to reduce the influence of particles misplacement. The new hydrocyclone integrates the advantages of both spiral inlet and tangential inlet. Through the analysis of separation performance, flow characteristics, and volume fraction distributions, an optimum design is identified. Compared to a standard hydrocyclone, the new design significantly improves tangential velocities, expands the locus of zero vertical velocity, and achieves more stable air core, symmetric radial and axial velocity distributions, as well as reduced eddy flow and short-circuit flow. This study offers a new perspective for improving hydrocyclone flows and performance.
Article
Computer Science, Interdisciplinary Applications
Jeff T. Gostick, Niloofar Misaghian, Jianhui Yang, Edo S. Boek
Summary: A new algorithm for simulating volume-controlled invasion of a non-wetting phase into voxel images is presented, offering advantages over traditional pressure-based invasion methods. By incrementally increasing saturation, the algorithm allows for accurate prediction of defending phase trapping and provides a capillary pressure curve with characteristic jumps. Results show that the proposed method is a superset of the morphological approach and can achieve similar results to multiphase lattice Boltzmann simulations in less time.
COMPUTERS & GEOSCIENCES
(2022)
Article
Chemistry, Analytical
Uihwan Kim, Joo-Yong Kwon, Taehoon Kim, Younghak Cho
Summary: This paper investigates the behavior of particles in microchannels under Newtonian and non-Newtonian fluids, comparing and studying their behavior through experiments and numerical simulations. The results show that in Newtonian fluids, particles exhibit multi-line focusing, while in non-Newtonian fluids, particles focus in a single line. In microchannels with equilateral hexagonal cross sections, particle focusing is tighter than in microchannels with rhombic cross sections. The simulations support the experimental observations that viscoelastic fluids significantly affect particle migration in both types of microchannels, due to the combined effects of inertia and elasticity.
Article
Polymer Science
Ahmad Fakhari, Celio Fernandes
Summary: This study presents the development of an interface-capturing method for simulating the motion of air bubbles in viscoelastic fluids. The proposed algorithm accurately captures interface curvature and can be applied to various fluids for buoyancy-driven rise simulations. It has potential applications in bubble columns in reactors, oil and gas mixtures, 3D printing, polymer processing, etc.
Article
Geochemistry & Geophysics
I Kovacs, L. Patko, N. Liptai, T. P. Lange, Z. Taracsak, S. A. P. L. Cloetingh, K. Torok, E. Kiraly, D. Karatson, T. Biro, J. Kiss, Zs Palos, L. E. Aradi, Gy Falus, K. Hidas, M. Berkesi, A. Koptev, A. Novak, V Wesztergom, T. Fancsik, Cs Szabo
Article
Geosciences, Multidisciplinary
Marta Berkesi, Eniko Bali, Robert J. Bodnar, Abel Szabo, Tibor Guzmics
Article
Geography, Physical
Nora Liptai, Thomas P. Lange, Levente Patko, Zsanett Pinter, Marta Berkesi, Laszlo E. Aradi, Csaba Szabo, Istvan J. Kovacs
Summary: In this study, the water contents in upper mantle xenoliths in the Carpathian-Pannonian region were comprehensively examined, revealing higher water contents in Tihany xenoliths compared to Flizes-to xenoliths. Differences in water contents may be influenced by factors such as eruption age and depth of origin. Additionally, variations in effective viscosities and electrical resistivities suggest that central locations have more rigid lithospheric mantles compared to marginal locations, potentially influenced by extension-related lithospheric thinning.
GLOBAL AND PLANETARY CHANGE
(2021)
Article
Geochemistry & Geophysics
Nora Liptai, Marta Berkesi, Levente Patko, Robert J. Bodnar, Suzanne Y. O'Reilly, William L. Griffin, Csaba Szabo
Summary: The study analyzed silicate melt inclusions to determine the composition and evolution of metasomatic melt in the upper mantle. The trapped metasomatic melt linked to wehrlite formation was found to be enriched in iron with a trace-element pattern similar to OIB, suggesting an intraplate mafic melt with a slightly different chemistry compared to the host basalt.
AMERICAN MINERALOGIST
(2021)
Article
Geochemistry & Geophysics
Levente Patko, Jakub Ciazela, Laszlo Elod Aradi, Nora Liptai, Bartosz Pieterek, Marta Berkesi, Marina Lazarov, Istvan Janos Kovacs, Francois Holtz, Csaba Szabo
Summary: Sulfides from lherzolite and wehrlite xenoliths in the Nograd-Gomor Volcanic Field were studied to understand the behavior of chalcophile and siderophile elements. Significant differences were found in the composition and distribution of sulfides between the two xenolith types, suggesting enrichment of sulfides and chalcophile elements in the subcontinental lithospheric mantle due to metasomatism.
Article
Geography, Physical
Istvan J. Kovacs, Nora Liptai, Alexander Koptev, Sierd A. P. L. Cloetingh, Thomas P. Lange, Liviu Matenco, Alexandru Szakacs, Mircea Radulian, Marta Berkesi, Levente Patko, Gabor Molnar, Attila Novak, Viktor Wesztergom, Csaba Szabo, Tamas Fancsik
Summary: The 'pargasosphere' hypothesis proposed by the author explains the role of MLDs in continental lithospheres and offers a mechanism for the formation of MLDs. The hypothesis also presents several empirically testable implications.
GLOBAL AND PLANETARY CHANGE
(2021)
Article
Geology
Tamas Spranitz, Jose Alberto Padron-Navarta, Csaba Szabo, Abel Szabo, Marta Berkesi
Summary: The primary multiphase fluid inclusions (MFI) in the Cabo Ortegal Complex (COC) in NW Spain were found to be formed under high-pressure metamorphic conditions. The mineral assemblage of MFI consists mainly of carbonates and silicates, with proportions of nitrogen, methane and carbon dioxide. Reactions between the MFI and the host minerals resulted in carbonation and hydration reactions. This study has important implications for global nitrogen and carbon cycling, as well as the supply of nitrogen and methane in subsurface-surface environments.
JOURNAL OF METAMORPHIC GEOLOGY
(2022)
Article
Geosciences, Multidisciplinary
Levente Patko, Zoltan Kovacs, Nora Liptai, Laszlo E. Aradi, Marta Berkesi, Jakub Ciazela, Karoly Hidas, Carlos J. Garrido, Istvan J. Kovacs, Csaba Szabo
Summary: The single-lithology and composite xenoliths from Mindszentkalla provide insights into the geochemical evolution of the subcontinental lithospheric mantle. These xenoliths show evidence of at least two metasomatic events, with the first event leading to orthopyroxene enrichment and the formation of harzburgites. The different domains of the composite xenoliths likely represent reaction products of variably evolved basaltic melts. The formation of these xenoliths is likely linked to past subduction of oceanic crust and plate extrusion.
FRONTIERS IN EARTH SCIENCE
(2022)
Article
Geosciences, Multidisciplinary
Noemi Halasz, Marta Berkesi, Tivadar M. Toth, Roger H. Mitchell, Ralf Milke, Tibor Guzmics
Summary: A detailed petrographic and mineralogical investigation of olivine-phlogopite micro-ijolite xenoliths from Oldoinyo Lengai, Tanzania reveals their complex evolutionary history and diverse textural features. The xenoliths show crystallization temperatures ranging from 1070-970 degrees C to 850-700 degrees C, controlled by perovskite-titanite equilibria under plutonic pressures. The presence of double coronas and compositional zonation in the xenoliths suggests early magma chamber processes and multiple magma injections followed by cooling periods. The study provides insights into the origin and formation processes of these micro-ijolite xenoliths.
JOURNAL OF AFRICAN EARTH SCIENCES
(2023)
Article
Geochemistry & Geophysics
Marta Berkesi, Justine L. Myovela, Gregory M. Yaxley, Tibor Guzmics
Summary: The study compares high temperature silicate-carbonatite immiscible melts with silica-undersaturated volcanic rocks from continental settings to understand the formation of calcite carbonatite rocks. Melt inclusions from the Kerimasi volcano in the East African Rift System show early formation of the rock and entrapment of melts at high temperatures and pressures. The presence of immiscible mafic-melilitite and Ca-Na-K-carbonatite melts suggests a continental rift setting and the crystallization of calcite carbonatite rocks.
GEOCHIMICA ET COSMOCHIMICA ACTA
(2023)
Article
Geochemistry & Geophysics
Tamas Spranitz, Csaba Szabo, Mattia Gilio, Matteo Alvaro, Michaela Blazekova, Patrik Konecny, Tamas Vaczi, Marta Berkesi
Summary: Fluid and mineral inclusions in metamorphic rocks play a crucial role in understanding fluid-involved processes in subduction zones. This study focuses on ultramafic granulite from the Cabo Ortegal Complex in Spain, using quartz-in-garnet and zircon-in-garnet Raman spectroscopy to determine the entrapment conditions of mineral and fluid inclusions. The findings confirm the reliability of elastic thermobarometry on mineral inclusions in determining the entrapment P-T conditions. Rating: 8 out of 10.
Article
Geosciences, Multidisciplinary
Matyas Hencz, Tamas Biro, Karoly Nemeth, Kristof Porkolab, Istvan Janos Kovacs, Tamas Spranitz, Sierd Cloetingh, Csaba Szabo, Marta Berkesi
Summary: This paper presents the results of using a GIS workflow to analyze the spatial distribution and temporal evolution of volcanoes in the Mio-Pleistocene monogenetic Bakony-Balaton Highland Volcanic Field (BBHVF) in Hungary. The study reveals the importance of the pre-existing structure of the upper lithosphere in the distribution of volcanic centers. The orientation of the volcanic field is found to correspond to the orientation of faults in the region, suggesting a dominant SW-NE direction. The proximity analysis also indicates the significance of thrust faults in the clustering of the volcanoes.
JOURNAL OF VOLCANOLOGY AND GEOTHERMAL RESEARCH
(2023)