期刊
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
卷 59, 期 -, 页码 173-185出版社
ELSEVIER
DOI: 10.1016/j.jtice.2015.09.017
关键词
Artificial neural network; Genetic algorithm; Methanol conversion to propylene; Design and optimization of catalyst; Bimetallic modification of H-ZSM-5
To enhance the propylene selectivity in catalytic conversion of methanol to propylene (MTP), the bimetallic catalysts were prepared by Mn/H-ZSM-5 with second metal of Ce, Cr, Fe and Ni. In order to design the bimetallic catalysts (M-Mn/H-ZSM-5; M: Ce, Cr, Fe and Ni) and to optimize the propylene selectivity, an artificial neural network (ANN) model was linked with genetic algorithm (GA). Investigation of the optimal catalyst preparation conditions (wt. % of second metal loading, calcination temperature and calcination time) and the atomic descriptors of second metal (electronegativity, melting enthalpy, atomic weight and ionization energy) were carried out by the ANN-GA model simultaneously. The model predicted that the maximum propylene selectivity was produced via Ce-Mn/H-ZSM-5 with the following catalyst preparation conditions: 2.46 wt. % of Ce loading, calcination temperature of 486 degrees C and calcination time of 4 h. The optimized propylene selectivity of model prediction and the experimental value were 543% and 54.8% respectively. The catalyst samples were characterized by XRD, FE-SEM, FT-IR, N-2 adsorption/desorption, NH3-TPD and ICP-AES. (C) 2015 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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