Article
Nanoscience & Nanotechnology
Matthew A. Browe, John Landers, Trenton M. Tovar, John J. Mahle, Alex Balboa, Wesley O. Gordon, Masafumi Fukuto, Christopher J. Karwacki
Summary: A novel strategy was developed to enhance the barrier protection of polyethylene oxide (PEO)-metal-organic framework (MOF) composite films by incorporating impermeable Laponite RD (LRD) clay platelets. The inclusion of LRD platelets improved the barrier performance of the films against toxic chemical threats while maintaining high water vapor transport rates. This approach establishes a new path for improving selective materials for chemical protection applications.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Materials Science, Multidisciplinary
Suhui Wang, Xu Zhang, Genwei Zhang, Tengxiao Guo, Xuequan Ding
Summary: This study optimized the performance of PbS quantum dot light sources by adjusting the ratio of QD solution to UV glue, matching chemical absorption spectra, and improving stability and light intensity. By selecting different QD-glue ratios, the PL peak of the light source can be adjusted, enabling qualitative and quantitative detection of chemicals.
Article
Polymer Science
Xucong Chen, Xue Li, Huijuan Zhang, Hong Li, Guiyou Wang, Yan Cui
Summary: In this study, the relationship between the diisocyanate structure and the protective properties of polyurethanes (PUs) was investigated. It was found that the diisocyanate structure had a significant influence on the adsorption and permeation behaviors of the PUs. The alicyclic PU showed the lowest adsorption and retention capacity, making it a potential candidate for protective topcoat PU material.
Article
Engineering, Environmental
Tommi Mikkonen, Daniel Luoma, Hanna Hakulinen, Goery Genty, Paula Vanninen, Juha Toivonen
Summary: High-profile assassination attempts have underscored the need for high-performance and field-deployable nerve agent (NA) sensors. In this study, a novel optical sensor based on Fourier transform spectroscopy and cantilever-enhanced photoacoustic detection was developed for the detection of gaseous NAs. The sensor demonstrated fast multi-species gas sensing with high sensitivity and selectivity in a small sample volume, which is advantageous for field analysis of limited NA samples. Future improvements could be achieved by developing more powerful supercontinuum light sources in the mid-infrared region.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Jin Young Seo, Younghan Song, Jung-Hyun Lee, Hyungsup Kim, Sangho Cho, Kyung-Youl Baek
Summary: A durable and environmentally friendly composite of nanocellulose/metal-organic framework aerogel was prepared for effective detoxification of chemical warfare agent simulants in both static and dynamic continuous flow systems. The composite showed high stability and efficiency in removing nerve agent simulants, making it a promising candidate for detoxification filters.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Engineering, Environmental
Juan Yang, Xiaoqian He, Jun Dai, Ran Tian, Dongsheng Yuan
Summary: The study demonstrates the catalytic detoxification of two chemical warfare agent simulants using ZnInS/UiO nanocomposites under simulated solar light. The enhanced detoxification efficiency of ZnInS/UiO is attributed to its photothermal effect and close interfacial contact in heterostructures, improving catalytic activity for nerve agent and mustard gas surrogates. The findings offer new opportunities for photo-assisted enhanced detoxification of CWAs with potential applications in multifunctional catalysts based on metal-organic frameworks.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
He Zhao, Cheng-an Tao, Shiyin Zhao, Xiaorong Zou, Fang Wang, Jianfang Wang
Summary: This study aims to develop highly efficient bifunctional catalysts for the simultaneous detoxification of nerve agent and blister agent, two of the deadliest chemical warfare agents. By introducing two porphyrin-based ligands (TCPP and PPIX) into two-dimensional ultrathin metal-organic framework materials (MOLs), the catalytic activity of the MOLs for nerve agent and blister agent simulants was investigated. The results showed that TCPP-functionalized MOL exhibited the highest catalytic activity for the degradation of blister agent simulant under solar light.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Analytical
Juan F. Ayala-Cabrera, Jasmin Turkowski, Florian Uteschil, Oliver J. Schmitz
Summary: A tube plasma ionization (TPI) open-air source for gas chromatography-mass spectrometry (GC-MS) was developed, and its ionization capabilities were tested using various analytes. Different discharge gases and auxiliary gases were investigated, along with the effects of adding water. Compared to other atmospheric pressure ionization sources, TPI showed a wider range of compound ionization and better detection capability.
ANALYTICAL CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Shiyu Zhang, Chenshan Dong, Yilun Wang, Jingjing Huang, Shaojin Gu, Hongjun Yang, Xin Liu, Weilin Xu, Dezhan Ye
Summary: A strategy for preparing MOF-808-loaded polypropylene nonwoven fabrics mediated by a TA-APTES hybrid coating was reported. The resulting fabric exhibited a rapid catalytic degradation rate for DMNP in a basic buffered condition.
Article
Chemistry, Analytical
Tao Lin, Jing Hu, Yujia Deng, Wen Zeng, Xiaoming Jiang, Xiandeng Hou
Summary: A miniaturized atomic absorption spectrometer (AAS) was proposed with a planar dielectric barrier discharge (DBD) microplasma as an atomizer, a charge coupled device (CCD) spectrometer as a spectral detector, and a hydride generation (HG) unit as a sampler. The method showed excellent analytical capability and enhancement effect in the determination of cadmium.
ANALYTICA CHIMICA ACTA
(2022)
Article
Chemistry, Inorganic & Nuclear
Eric M. Johnson, Mikaela C. Boyanich, Bradley Gibbons, Nicholas S. Sapienza, Xiaozhou Yang, Ayman M. Karim, John R. Morris, Diego Troya, Amanda J. Morris
Summary: Metal-organic frameworks (MOFs) have limitations in the hydrolysis of nerve agents due to the stable bridging configuration between the hydrolyzed products and the MOF nodes. This study presents two copper single atom-modified UiO-66 MOFs, which exhibit similar reactivity to the native MOF under aqueous conditions, suggesting the influence of the copper coordination environment on product inhibition.
INORGANIC CHEMISTRY
(2022)
Review
Chemistry, Analytical
Meng Chen, Yiling Li, Baoqiang Li, Zhongyao Zhang, Lin Zhang, Cuiping Li, Qiang Ma
Summary: In the face of international conflicts and terrorism, the threat of unconventional warfare agents, especially biological agents, is a constant concern. Therefore, ambient ionization mass spectrometry provides promising opportunities for rapid and accurate screening and identification of biological weapons.
MICROCHEMICAL JOURNAL
(2023)
Article
Engineering, Chemical
Rongjie Yi, He Guo, Huijuan Wang, Daolin Du, Qi Zhang, Chengwu Yi
Summary: This study investigated the degradation of oxytetracycline in aqueous solution by humid O2 strong ionization dielectric barrier discharge and identified optimal parameters for efficiency. Increasing the input voltage and solution pH can improve OTC removal efficiency, while inhibitors and organic matter can reduce efficiency. Compared to dry O2 strong ionization dielectric DBD, the results showed better performance with humid O2 strong ionization discharge DBD.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Nanoscience & Nanotechnology
Xiuling Zhang, Yaxin Sun, Yuanfeng Liu, Zhenyu Zhai, Shiquan Guo, Lichong Peng, Yue Qin, Congju Li
Summary: This study developed a scalable and controllable strategy to fabricate UiO-66-NH2 on electrospun polyacrylonitrile nanofibers (UiO-66-NH2 fabrics) to capture and catalyze 2-chloroethyl ethyl sulfide (CEES) effectively for self-detoxification. The obtained UiO-66-NH2 fabrics are capable of specific surface area, porosity, crystallinity, and abundant catalytic active sites, enabling efficient removal of CEES up to 97.7% after 48 h. The nanofibrous fabrics possess air-permeable, washable, flexible, and lightweight features, ensuring promising engineering applications for protective clothing.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Toxicology
Akram Elmahdy, Yachao Cao, Xiaoying Hui, Howard Maibach
Summary: The study showed that human scalp has a greater total skin absorption of chemical warfare simulants compared to abdominal skin, indicating the potential importance of high follicular density regions in percutaneous penetration.
JOURNAL OF APPLIED TOXICOLOGY
(2021)