期刊
CARBOHYDRATE POLYMERS
卷 306, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2023.120587
关键词
Starch; Poly(vinyl alcohol); Organohydrogel; Recyclability; Wide temperature adaptability; Flexible all -solid-state supercapacitors
In this study, a starch/PVA/dimethyl sulfoxide/CaCl2 (SPDC) organohydrogel was prepared by the freezing-thawing method. The addition of dimethyl sulfoxide (DMSO) and CaCl2 enhanced the mechanical properties and widened the working temperature range of the starch/PVA hydrogel. The SPDC organohydrogel exhibited high strength, toughness, and good recyclability, and was used as the electrolyte for flexible supercapacitors, showing high capacitance retention rates and wide temperature adaptability.
Hydrogel electrolytes have shown great promise in the field of flexible energy storage. However, the conventional hydrogel electrolytes have poor mechanical properties and are not recyclable. In addition, conventional hydrogel electrolytes cannot adapt to low and high temperature operating environments. In this study, starch/ PVA/dimethyl sulfoxide/CaCl2 (SPDC) organohydrogel was prepared by the freezing-thawing method. Dimethyl sulfoxide (DMSO) and CaCl2 was introduced to enhance the mechanical properties and widen the working temperature range of the starch/PVA hydrogel. The SPDC organohydrogel had high strength, toughness and good recyclability. The SPDC organohydrogel and the recycled SPDC organohydrogel was used as the electrolyte to assemble the flexible supercapacitor with activated carbon as the electrode. The supercapacitor prepared by SPDC organohydrogel electrolyte exhibited high areal capacitance of 156.50 mF/cm2 at a current density of 1 mA/cm2 and high capacitance retention rate of 82.23 % after 8000 cycles of charging and discharging. The supercapacitor prepared by the recycled organohydrogel electrolyte exhibited a high capacitance retention rate of 97.58 %. In addition, the supercapacitor could withstand different angular bending shapes and had wide temperature adaptability from -20 degrees C to 80 degrees C. The work provided a new version for the development of green hydrogel electrolyte for all-solid-state supercapacitor.
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