期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 3, 页码 742-745出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.5b11441
关键词
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资金
- Singapore Ministry of Education Academic Research Fund [MOE2013-T2-2-057, MOE2014-T1-001-021]
- Chinese Scholarship Counsel
Copper complexes of phosphoramidites efficiently catalyzed asymmetric addition of arylboron reagents to acyclic enones. Importantly, rare 1,4-insertion of arylcopper(I) was identified which led directly to O-bound copper enolates. The new mechanism is fundamentally different from classical oxidative addition/reductive elimination of organocopper(I) on enones.
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