期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 17, 页码 5539-5542出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b02914
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资金
- University of Delaware (UD)
- Research Corporation (Cottrell Scholars Program)
- NSF (CAREER) [CHE1254360]
- NSF
- NIH
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1254360] Funding Source: National Science Foundation
We report the first example of a boryl-Heck reaction using an electrophilic boron reagent. This palladium-catalyzed process allows for the conversion of terminal alkenes to trans-alkenyl boronic esters using commercially available catecholchloroborane (catBCl). In situ transesterification allows for rapid access to a variety of boronic esters, amides, and other alkenyl boron adducts.
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