期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 138, 期 24, 页码 7456-7459出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b02495
关键词
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资金
- 973 Project [2015CB856600]
- National Natural Science Foundation of China [21472179, 21272221]
- Fundamental Research Funds for the Central Universities [WK 2060190026, 3430000001]
- China Postdoctoral Science Foundation [2015M581995]
A Pd/norbornene/Cu cooperative catalysis for the efficient synthesis of 2-(arylthio)aryl ketones, from aryl halides and thioesters has been developed. The first example of cooperative catalysis by palladium, norbornene, and copper, wherein the C(O)-S bond of thioesters is cleaved by a Pd-II palladacycle with the assistance of CuI, has been observed.
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