Article
Chemistry, Multidisciplinary
Gaoxue Jiang, Jiandong Liu, Jian He, Huaping Wang, Shihan Qi, Junda Huang, Daxiong Wu, Jianmin Ma
Summary: This study proposes a novel electrolyte additive to optimize the electrode electrolyte interface and address the issues caused by high voltage. The additive can form a dense and stable solid electrolyte interphase, suppress the growth of lithium dendrites, and enhance lithium ion transport efficiency. Additionally, it can protect the electrolyte interface from corrosion. Experimental results demonstrate that lithium batteries using this electrolyte exhibit improved cycling life and energy density under high voltage.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Xin Li, Jiandong Liu, Jian He, Huaping Wang, Shihan Qi, Daxiong Wu, Junda Huang, Fang Li, Wei Hu, Jianmin Ma
Summary: The study focuses on designing a gradient lithium oxysulfide/uniform lithium fluoride-type SEI using HFPTf as an electrolyte additive, which improves the cycling stability of Li-ion batteries and inhibits the growth of Li dendrites. Additionally, the formation of a uniform and stable CEI on the cathode surface with HFPTf-containing electrolyte enhances capacity retention in Li||NCM811 batteries.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Physical
Jiandong Liu, Mingguang Wu, Xin Li, Daxiong Wu, Huaping Wang, Junda Huang, Jianmin Ma
Summary: Constructing robust electrode electrolyte interphases (EEIs) with polar amide groups and a Li3N/LiF heterostructure can enhance the charge cut-off voltage of LiCoO2 at 4.6 V, improving the battery density and addressing the challenge of structural instability.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Gaoxue Jiang, Jiandong Liu, Zhongsheng Wang, Jianmin Ma
Summary: A high-performance non-flammable electrolyte is designed by using 1.5 m LiTFSI in propylene carbonate (PC)/triethyl phosphate (TEP) (4:1 by vol.) with 4-nitrophenyl trifluoroacetate (TFANP) as the additive. This electrolyte can facilitate the formation of LiF-rich solid electrolyte interphase (SEI) on the Li anode surface and cathode electrolyte interphase (CEI) on the cathode surface, suppressing the growth of Li dendrites and reducing the continuous electrolyte consumption. The Li||LiNi0.6Co0.2Mn0.2O2 battery with this electrolyte shows excellent cycling stability and rate performance.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Chemistry, Multidisciplinary
Yiming Sui, Xiulei Ji
Summary: The narrow electrochemical stability window of water poses a challenge to the development of aqueous electrolytes. Unlike non-aqueous electrolytes, additional components reactions are required in aqueous electrolytes to facilitate the formation of desired solid electrolyte interphase (SEI) and cathode electrolyte interphase (CEI).
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Girum Girma Bizuneh, Chunlei Zhu, Junda Huang, Huaping Wang, Shihan Qi, Zhongsheng Wang, Daxiong Wu, Jianmin Ma
Summary: An electrolyte additive strategy is proposed to improve the stability and voltage of Li||LiCoO2 batteries, by constructing efficient LiNxOy-contained cathode electrolyte interphase and LiF-rich solid electrolyte interphase. The Li||LiCoO2 battery can operate stably up to 4.6 V, with high specific capacity and capacity retention.
Article
Chemistry, Multidisciplinary
Yan Jin, Yaobin Xu, Biwei Xiao, Mark H. Engelhard, Ran Yi, Thanh D. Vo, Bethany E. Matthews, Xiaolin Li, Chongmin Wang, Phung M. L. Le, Ji-Guang Zhang
Summary: This study reports an advanced electrolyte based on sodium bis(fluorosulfonyl)imide-triethyl phosphate, which is highly stable against a high-voltage cathode, enabling long-term cycling of sodium batteries. The stabilization of the high-voltage cathode is attributed to the formation of a stable electrode/electrolyte interphase layer, obtained mainly through salt decomposition, which suppresses transition metal dissolution and surface reconstruction on the cathode.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Le Anh Ma, Andrew J. Naylor, Leif Nyholm, Reza Younesi
Summary: This study investigates the impact of electrolyte chemistry on the dissolution of the solid electrolyte interphase (SEI) in sodium-ion batteries, using beta-alumina as a sodium-conductive membrane to prevent crosstalk. The research found that the solubility of SEI species in the electrolyte can reach up to 30% after a 50-hour pause, and saturation of the electrolyte with these SEI species can counteract aging due to SEI dissolution.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Materials Science, Multidisciplinary
Ke Sun, Zhangquan Peng
Summary: A robust electrode-electrolyte interface is crucial for battery systems, especially in the development of new battery technologies. The introduction of artificial Li-alloying intermetallic interphases has significantly improved the stability and performance of lithium metal batteries and solid-state batteries.
Article
Nanoscience & Nanotechnology
J. Padmanabhan Vivek, Nina Meddings, Nuria Garcia-Araez
Summary: The addition of water as an electrolyte additive in NASICON-type solid electrolytes has been shown to effectively suppress interface resistance between solid and liquid electrolytes, leading to potential enhancements in energy density and roundtrip efficiency of Li-S or Li-O-2 batteries.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Review
Materials Science, Multidisciplinary
Enhui Wang, Yubin Niu, Ya-Xia Yin, Yu-Guo Guo
Summary: This passage discusses the commercial demands for sodium ion batteries (SIBs) for large-scale energy storage after rapid development over the past decade. It highlights the importance of electrode-electrolyte interphases in determining battery performance and reviews current research and challenging issues related to SIB interphases. The passage also emphasizes the fundamental understanding of interphase layers, interphase manipulation via parental electrolyte, and potential effects from chosen electrodes to build stable Na-based interphase layers for high-energy and long-life-span batteries.
ACS MATERIALS LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Jun-Fan Ding, Rui Xu, Nan Yao, Xiang Chen, Ye Xiao, Yu-Xing Yao, Chong Yan, Jin Xie, Jia-Qi Huang
Summary: The cosolvents play a critical role in the solvation structure of Li+ and the formation of SEI on working Li metal anodes, with NL cosolvents enhancing the interaction between anion and Li+ to induce an anion-derived inorganic-rich SEI. A solvent with proper relative binding energy toward Li+ and dielectric constant is suitable as NL cosolvent.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Physical
Wen-Peng Wang, Juan Zhang, Jia Chou, Ya-Xia Yin, Ya You, Sen Xin, Yu-Guo Guo
Summary: The energy storage technology based on Li-S systems is not yet commercialized due to unstable electrochemistry at the electrode-electrolyte interface. By solidifying the cathode-electrolyte interface, the Li-S battery's electrochemical performance could be improved.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Mengfan Zhou, Panxing Bai, Xiao Ji, Jixing Yang, Chunsheng Wang, Yunhua Xu
Summary: Potassium ion batteries are considered a promising candidate for future energy storage devices due to their cost-effectiveness, high-voltage, and high-power operation. In addition to electrode materials, electrolytes also play a crucial role in determining cell performance. This Progress Report summarizes the research progress of electrolytes in PIBs and provides comprehensive guidance on the design of electrolyte systems for high performance PIBs.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Weixia Lv, Lucheng Li, Jun Chen, Caixia Ou, Qian Zhang, Shengwen Zhong, Hua Wang, Lijue Wu, Haikuo Fu
Summary: The novel high-voltage electrolyte additive TTD was found to significantly improve the capacity, cycle stability, and rate capability of batteries at high voltages. It effectively inhibits electrolyte decomposition by forming a stable cathode electrolyte interphase film. This additive could offer a cost-effective solution for high-performance high-voltage electrolytes.
Article
Engineering, Environmental
Honghao Liu, Runming Tao, Chi Guo, Wang Zhang, Xiaolang Liu, Pingmei Guo, Tianyu Zhang, Jiyuan Liang
Summary: A novel clay/cross-linked network polymer-based artificial SEI layer (NCL) is developed to prevent the formation of lithium dendrites, leading to enhanced cyclability and excellent mechanical performance in lithium metal batteries. The NCL-protected LM symmetrical cells exhibit stable cycling performance for over 1000 hours, while the NCL-Li vertical bar Cu half-cells demonstrate dendrite-free and reversible Li deposition with a high Coulombic efficiency of 99% for 170 cycles. The LiFePO4 full-cell and LiNi0.8Co0.1Mn0.1O2-coupled pouch-cells also achieve outstanding capacity retention over multiple cycles and show reliable performance under different damage conditions, highlighting the potential of NCL for practical application in high-performance LMBs.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Runming Tao, Tao Wang, Juntian Fan, Harry M. Meyer, Albina Y. Borisevich, Chi-Linh Do-Thanh, Sheng Dai
Summary: A facile in-situ ionothermal strategy was developed to synthesize carbon/oxide composites with nanoporous structure. The use of ionic liquids as solvents, templates, and carbon sources greatly improved the carbon yield and enhanced the electrochemical performance of the composites.
Article
Energy & Fuels
Jixing Liu, Meizan Jing, Runming Tao, Weiyu Song, Huifang Cheng, Huaming Li, Zhen Zhao, Jian Liu, Wenshuai Zhu, Sheng Dai
Summary: This study investigates the active sites and their properties in CO oxidation of Cu-based catalysts. The experimental results demonstrate that Cu+ species are the main active sites for CO oxidation. DFT calculations reveal that Cu+ species greatly facilitate the adsorption of CO and O2, and reduce the desorption energy of CO2, thereby significantly enhancing the catalytic activity of CO oxidation.
Article
Materials Science, Multidisciplinary
Jiyuan Liang, Zhen Wang, Litao Huang, Pan Zou, Xiaolang Liu, Qian Ni, Xinyu Wang, Wenjun Wang, Runming Tao
Summary: A novel nitrogen-doped graphene with different microstructures is synthesized through an in situ interlamination self-assembling method, using in situ formed Fe3(PO4)2 and organoamine as the catalyst and carbon source, respectively. Bubble-like and sheet-like nitrogen-doped graphene are obtained by tuning the alkyl chain length in organoamine, octylamine, and dodecylamine. The as-prepared graphene electrode material exhibits good rate capability and cyclic performance, delivering promising practicality for energy storage applications.
ACS MATERIALS LETTERS
(2023)
Article
Electrochemistry
Runming Tao, Tianyu Zhang, Xiao-Guang Sun, Chi-Linh Do-Thanh, Sheng Dai
Summary: A new W6+-doped TiNb2O7 material with a nanoporous structure (NPTWNO) was prepared through an ionothermal synthesis-assisted doping strategy. The improved Li+ diffusion coefficient of NPTWNO suggests that the ionic-liquid-templated nanoporous architecture enhances Li+ diffusion kinetics. The doped W6+ successfully boosts the electronic conductivity by narrowing the conduction-valance bandgap, as revealed by the density functional theory computational study.
BATTERIES & SUPERCAPS
(2023)
Article
Nanoscience & Nanotechnology
Runming Tao, Susheng Tan, Harry M. Meyer III, Xiao-Guang Sun, Bryan Steinhoff, Kahla Sardo, Amer Bishtawi, Tillman Gibbs, Jianlin Li
Summary: Dry processing is a promising method for high-performance and low-cost lithium-ion battery manufacturing which uses polytetrafluoroethylene (PTFE) as a binder. The electrochemical stability of PTFE binder in the cathodes and the chemistry of the cathode electrolyte interphase (CEI) layers are studied by cycling the high-loading dry-processed electrodes in electrolytes with LiPF6 or LiClO4 salt. The detection of LiF confirms that PTFE undergoes side reactions in the cathodes, and the thickness of the CEI layer is found to be much thicker when LiPF6 is used as the electrolyte salt compared to LiClO4.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Engineering, Industrial
Jaswinder Sharma, Zoriana Demchuk, Georgios Polizos, Nihal Kanbargi, Runming Tao, Amit Naskar, Jianlin Li
Summary: The development of high-voltage cathode materials driven by high energy density demand requires improved electrochemical stability of battery components. A metal-free composite film containing carbon fiber, carbon nanotube, and polymer was developed to replace aluminum foil as a cathode current collector. The CF-CNT-P composite demonstrated excellent electrochemical and thermal stability, with cathodes coated on it showing improved performance compared to those deposited on conventional aluminum foil. The lightweight and simplified recycling process further contribute to its potential in high-energy-density batteries.
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY
(2023)
Article
Chemistry, Physical
Runming Tao, Bryan Steinhoff, Conrad H. Sawicki, Jaswinder Sharma, Kahla Sardo, Amer Bishtawi, Tillman Gibbs, Jianlin Li
Summary: Dry processing of lithium-ion battery electrodes is considered a promising strategy for manufacturing, but little is known about the impact of dry mixing. This study monitors the degree of dry mixing using dry mixing time and prepares a series of dry-processed electrodes with different degrees of dry mixing. It reveals that the degree of dry mixing significantly affects the morphology, homogeneity of electrode components, and PTFE fiberization, leading to variations in the mechanical strength and electrochemical performance of dry-processed electrodes. It is suggested that a moderate degree of dry mixing is preferred for high-performance dry-processed lithium-ion battery electrodes.
JOURNAL OF POWER SOURCES
(2023)
Article
Electrochemistry
Zhijia Du, Zhenzhen Yang, Runming Tao, Vadim Shipitsyn, Xianyang Wu, David C. Robertson, Kelsey M. Livingston, Shae Hagler, James Kwon, Lin Ma, Ira D. Bloom, Brian J. Ingram
Summary: In this study, a novel high-performance electrolyte (HPE) consisting of LiFSI, LiPF6, and carbonates is proposed for extreme fast charging (XFC) in lithium-ion batteries for electric vehicles. The HPE exhibits high ionic conductivity and excellent electrochemical stability at a high charging rate of 6-C, leading to improved discharge specific capacity and excellent long-term cyclability up to 1500 cycles under XFC conditions.
BATTERIES & SUPERCAPS
(2023)
Article
Engineering, Environmental
Xiang Lyu, Yaocai Bai, Jianlin Li, Runming Tao, Jun Yang, Alexey Serov
Summary: This study evaluated two commercially available stainless steel mesh substrates (316 SS and 304 SS) as electrodes for oxygen evolution reaction (OER) in natural seawater electrolysis. The results show that 304 SS is less stable against corrosion under neutral and low alkaline seawater electrolytes due to metal dissolution and chlorine evolution reaction (CER), while 316 SS outperforms 304 SS in terms of electrocatalytic activity and corrosion resistance. The performance of 304 SS is comparable to 316 SS under high alkaline seawater electrolyte, where CER and metal dissolution are suppressed by OER.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Electrochemistry
Runming Tao, Tianyu Zhang, Xiao-Guang Sun, Chi-Linh Do-Thanh, Sheng Dai
Summary: This study presents an ionothermal synthesis-assisted doping strategy to prepare a nanoporous W6+-doped TiNb2O7 material (NPTWNO) with improved electronic conductivity and lithium ion diffusion coefficient. The doped W6+ successfully narrows the conduction-valance bandgap and improves the electrochemical performance of NPTWNO, leading to fast-rechargeable lithium-ion batteries.
BATTERIES & SUPERCAPS
(2023)
Article
Chemistry, Physical
Jiyuan Liang, Runming Tao, Ji Tu, Chi Guo, Kang Du, Rui Guo, Wang Zhang, Xiaolang Liu, Pingmei Guo, Deyu Wang, Sheng Dai, Xiao-Guang Sun
Summary: This study presents a novel 3D densely packed multifunctional crosslinked gel polymer electrolyte (PHGPE) with a compact-stacked and crosslinked micro-sphere structure, which enables uniform Li plating/stripping and robust solid electrolyte interphases (SEIs) formation. The PHGPE shows excellent cyclability and compatibility with high-voltage cathodes, opening up new possibilities for high-performance lithium metal batteries (LMBs).
JOURNAL OF MATERIALS CHEMISTRY A
(2022)