Compression molding of algae fiber and epoxy composites: Modeling of elastic modulus

The demand for natural fiber composites in the automotive industry in both Europe and the United States has been forecasted to increase in the coming years. The natural fiber composites based on highly commercialized fibers such as flax, hemp, and sisal has grown to become an important sector of polymeric composites. However, little attention has been addressed to expanding natural fiber composites to include new sources of emerging natural reinforcements, such as reclaimed algae fibers, that have a multiple environmental benefits. Not only are extracted algae fibers biodegradable, the reclamation process has the added benefit of restoring health of waterways choked with algae. This study focuses on the processability of algae fiber-epoxy composites. Short fibers, chemically extracted from raw reclaimed algae, were prepared for natural fiber composite products in two ways. First, randomly oriented mats were produced using the wet-laid process to create layered, compression-molded laminates. Second, loose fibers were dispersed directly into the thermoset matrix to produce a bulk molding compound that was further compression molded into composite lamina. The effect of processing variables such as compaction pressure, temperature, and time were addressed. Moreover, the effect of fiber volume fraction (upsilon(f)) and fiber form were considered. Enhanced mechanical properties were found when 56% upsilon(f) algae fiber was used for the compression-molded laminates composite. This variant exhibited an improvement on the flexural and tensile modulus of 70% and 86% when compared to the neat epoxy. However, the volume of porosity on the same variant was 11% due to lack of compression in some of the fibers. The effect of porosity on the theoretical stiffness was estimated by using the Cox-Krenchel model. Furthermore, an empirical exponential model was formulated to characterize the multi-scale effect of compaction pressure on the overall fiber volume fraction, upsilon(f).