4.6 Article

Cellulose-based Ultralong Room-Temperature Phosphorescence Nanomaterials with Tunable Color and High Quantum Yield via Nano-Surface Confining Effect

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RESEARCH
卷 2023, 期 -, 页码 -

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AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.34133/research.0029

关键词

Phosphorescence; Cellulose nanocrystals; Cellulose derivatives; Nanomaterials; Security inks

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A new principle for constructing ecofriendly color-tunable organic room-temperature phosphorescence (RTP) nanomaterials based on the nano-surface confining effect was discovered. Cellulose nanocrystal (CNC) immobilized cellulose derivatives (CX) with aromatic substituents effectively inhibit the motion of cellulose chains and luminescent groups, suppressing non-radiative transitions. The introduction of different CX and regulation of CX/CNC ratio allows for finely adjusting the RTP emission.
How to achieve multicolor organic room-temperature phosphorescence (RTP) is still challenging and striking. Herein, we discovered a new principle to construct ecofriendly color-tunable RTP nanomaterials based on the nano-surface confining effect. Cellulose nanocrystal (CNC) immobilized cellulose derivatives (CX) containing aromatic substituents via hydrogen-bonding interactions, which effectively inhibit the motion of cellulose chains and luminescent groups to suppress the non-radiative transitions. Meanwhile, CNC with a strong hydrogen bonding network can isolate oxygen. CX with different aromatic substituents regulate the phosphorescent emission. After mixing CNC and CX directly, a series of polychromatic ultralong RTP nanomaterials were obtained. The RTP emission of the resultant CX@CNC can be finely adjusted through the introduction of various CX and the regulation of the CX/CNC ratio. Such a universal, facile and effective strategy can be used to fabricate various colorful RTP materials with wide color gamut. Because of the completely biodegradability of cellulose, the multi-color phosphorescent CX@CNC nanomaterials can be used as eco-friendly security inks to fabricate disposable anti-counterfeiting labels and information-storage patterns via conventional printing and writing processes.

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