期刊
CHEMISTRYSELECT
卷 7, 期 43, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202202977
关键词
Epoxidation; Oxirane ring opening; DHSA; Polyols; Oleic acid
资金
- Universiti Teknologi MARA [600-RMC/GIP 5/3 (099/2021)]
This study investigated the effect of catalyst type and loading on the ring opening of epoxide groups using performic acid. The results showed that zeolite catalyst with a loading of 0.2 g achieved the highest conversion of oxirane. Fourier-transform infrared spectroscopy confirmed the impact of the epoxy ring location on the hydroxyl group.
Numerous academics worldwide are interested in utilizing waste as a resource to produce an epoxide. Epoxidation/ring-opening of oxirane is a common method for producing polyols from vegetable oil. This study examined the effect of the catalyst type and loading on the ring opening of epoxide groups by utilizing performic acid generated in situ. The outcomes demonstrated that the zeolite catalyst at 0.2 g loading produced the highest conversion of oxirane (RCO%). The FTIR data showed that the epoxy ring group's location caused the hydroxyl group's (O-H) to be observed at 3100-3600 cm(-1) in the placement of the epoxy ring group (C-O-C) at 1210-1250 cm(-1). Finally, optimization and kinetic modeling using artificial neural networks, abbreviated as Neural Network, is a model of the human brain that is abstracted, simulated, and trained to obtain the value of R closest to 1.
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