4.8 Article

Counter electrode electrocatalysts from one-dimensional coaxial alloy nanowires for efficient dye-sensitized solar cells

期刊

JOURNAL OF POWER SOURCES
卷 302, 期 -, 页码 361-368

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2015.10.083

关键词

Dye-sensitized solar cells; Alloy electrocatalysts; Counter electrodes; Core/shell nanowires

资金

  1. Fundamental Research Funds for the Central Universities [201313001, 201312005]
  2. Shandong Province Outstanding Youth Scientist Foundation Plan [BS2013CL015]
  3. Shandong Provincial Natural Science Foundation [ZR2011BQ017]
  4. Research Project for the Application Foundation in Qingdao [13-4-198-jch]
  5. National Natural Science Foundation of China [21503202, U1037604]
  6. National Key and National Key Technology Support Program [2012BAB15B02]

向作者/读者索取更多资源

Pursuit of cost-effective counter electrode (CE) electrocatalysts with no sacrifice of photovoltaic performances has been a persistent objective for advanced dye-sensitized solar cell (DSSC) platforms. Here we demonstrate the experimental realization of CE electrocatalysts from Cu@M@Pt (M = Fe, Co, Ni) coaxial alloy nanowires for efficient DSSCs. The reasonable electrocatalytic activity is attributed to work function matching of alloy CEs to potential of I-/I-3(-) and redistribute the electronic structure on the Pt surface. In comparison with 8.48% for the Pt nanotube CE based DSSC, the solar cells yield power conversion efficiencies up to 8.21%, 7.85%, and 7.30% using Cu@Fe@Pt, Cu@Co@Pt, and Cu@Ni@Pt NVVs, respectively. This work represents an important step forward, as it demonstrates how to make the CE catalyst active and to accelerate the electron transport from CE to electrolyte for high-efficiency but cost-effective DSSC platforms. (C) 2015 Elsevier B.V. All rights reserved.

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