Review
Nanoscience & Nanotechnology
Lin Han, Tiefeng Liu, Ouwei Sheng, Yujing Liu, Yao Wang, Jianwei Nai, Liang Zhang, Xinyong Tao
Summary: Silicon is promising for lithium storage due to its high capacity and low working platform, but volume changes during cycling lead to material pulverization and electrode cracking. A robust binder is essential for maintaining Si electrode integrity, yet its role in modulating the chemical composition and spatial distribution of the SEI layer is often overlooked.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Weibo Huang, Yan Wang, Linze Lv, Guobin Zhu, Qunting Qu, Honghe Zheng
Summary: To construct high-energy-density silicon-based Li-ion batteries, it is crucial to optimize and build a robust solid electrolyte interphase (SEI) to overcome the severe side reactions caused by volume changes in silicon (Si) anodes. This study combines electrolyte design and surface modification to create a phenyl trifluoromethanesulfonimide (PTFSI) interfacial layer on the Si surface, with additive functions. The resulting customized PTFSI interfacial layer modulates the solvation/desolvation reaction mechanism at the electrode interface, forming an artificial SEI structure composed of oligomers and inorganic salts. This structure exhibits fast ionic conductivity, reduces electrolyte consumption, and maintains the integrity of the electrode structure, leading to significantly improved rate capability and cycling performance of the optimized Si@PTFSI anode.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Haneol Kang, Hoon Kim, Chuleun Yeom, Moon Jeong Park
Summary: In this study, electrolyte additives were designed and synthesized for lithium batteries with an Si-graphite composite (SGC) anode to improve their rate performance and cycle stability. A hybrid artificial solid-electrolyte interphase (SEI) was formed on the anode surface through a combination of fluoroethylene carbonate (FEC) and dilithium vinylphosphonate (VPLi), resulting in enhanced capacity retention and rate capability.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Thomas F. Malkowski, Zhenzhen Yang, Robert L. Sacci, Stephen E. Trask, Marco-Tulio F. Rodrigues, Ira D. Bloom, Gabriel M. Veith
Summary: A new protocol was developed to compare battery life by using a constant potential and monitoring the current needed to maintain the potential. The results showed that EC and LiPF6 led to higher current and poorer passivation, while EMC had no effect on passivation. The mole fractions of the components also affected the composition of the solid-electrolyte interphase (SEI). Higher LiPF6 content resulted in increased LiF and current, but did not enhance passivation on the silicon surface. Comparing different compounds, it was found that EC did not generate a passivating SEI, while other compounds showed varying levels of passivation.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Chen Fang, Andrew Dopilka, Yueran Gu, Vassilia Zorba, Robert Kostecki, Gao Liu
Summary: This study demonstrates the applicability of small-molecule Langmuir-Blodgett films in electrode interface engineering for the development of lithium-ion batteries. The thin molecular films generated through the Langmuir-Blodgett technique were found to effectively regulate the electrochemical behavior of silicon electrodes in different electrolyte solutions.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Yu-Hsing Lin, Liang-Ting Wu, Yu-Ting Zhan, Jyh-Chiang Jiang, Yuh-Lang Lee, Jeng-Shiung Jan, Hsisheng Teng
Summary: Lithium-metal batteries with limited-Li anodes are crucial for high-energy storage. We engineer the self-assembly formation of solid-electrolyte interphase (SEI) in a gel polymer electrolyte (GPE) to control Li-deposition behavior and enhance reversibility.
ENERGY STORAGE MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Yongil Kim, Dominik Stepien, Hyein Moon, Kay Schoenherr, Benjamin Schumm, Matthias Kuenzel, Holger Althues, Dominic Bresser, Stefano Passerini
Summary: In order to increase the energy density of lithium batteries, the development of an anode with higher energy density than graphite or carbon/silicon composites is necessary. The use of metallic lithium has gained attention, however, safety issues and poor Coulombic efficiency hinder its practical application in lithium-metal batteries. A report focuses on the development of an artificial interphase to improve the reversibility of the lithium stripping/plating process and suppress parasitic reactions with the electrolyte. The modified lithium-metal electrodes show improved cycle life and high energy performance, highlighting the potential of the tailored interphase.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Weibo Huang, Yan Wang, Linze Lv, Wei Wang, Chengchang Jin, Guobin Zhu, Qiang Shi, Qunting Qu, Chao Jin, Honghe Zheng
Summary: A novel multifunctional surface modifier HEDP is developed to address the fundamental challenges of using FEC electrolyte additive and PVDF binder in Si-based batteries. The Si@HEDP anode exhibits excellent electrochemical performance, maintaining a high reversible capacity after 500 cycles.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Physical
Rongxian Wu, Xiaofan Du, Tao Liu, Xiangchun Zhuang, Peng Guan, Bingqian Zhang, Shenghang Zhang, Chenhui Gao, Gaojie Xu, Xinhong Zhou, Guanglei Cui
Summary: By pre-constructing an artificial SEI layer, the modified SiOx anode exhibits higher ICE, better capacity retention and superior rate capability, improving the applicability and performance of SiOx-based anodes.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Yi-Fan Tian, Shuang-Jie Tan, Zhuo-Ya Lu, Di-Xin Xu, Han-Xian Chen, Chao-Hui Zhang, Xu-Sheng Zhang, Ge Li, Yu-Ming Zhao, Wan-Ping Chen, Quan Xu, Rui Wen, Juan Zhang, Yu-Guo Guo
Summary: This study focuses on optimizing the anion-solvent interactions in ether-based electrolytes to improve the stability of both pure-SiOx anodes and LiNi0.8Mn0.1Co0.1 O2 cathodes. The optimized electrolyte enables stable cycling performance over 500 cycles in a full cell, demonstrating its practical prospects for high-energy density lithium-ion batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Weibo Huang, Yan Wang, Linze Lv, Xiang Li, Yueyue Wang, Wei Zheng, Honghe Zheng
Summary: To address the interface side reactions caused by volume expansion of Si particles, beneficial groups of binder and electrolyte were introduced on Si surface, forming a trinity functional layer. This layer enhances mechanical strength, restrains harmful reactions, and maintains efficient ion/electron transport, improving the overall performance of the Si electrode.
Article
Chemistry, Physical
Laura C. Merrill, Samantha G. Rosenberg, Katherine L. Jungjohann, Katharine L. Harrison
Summary: Research on lithium metal is focused on achieving highly reversible lithium electrodeposition/dissolution for long cycle life. The extent of self-discharge can be controlled by increasing plated lithium capacity, tuning electrolyte chemistry, incorporating rest periods, or introducing lithiophilic materials. The dominant self-discharge mechanism is shown to be a morphological process rather than an irreversible chemical process.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Lukas Koebbing, Arnulf Latz, Birger Horstmann
Summary: This study explains the observed voltage hysteresis in silicon nanoparticle anodes through a chemo-mechanical model and identifies the viscosity of the solid-electrolyte interphase as the cause.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Electrochemistry
Maitri Uppaluri, Krishna Shah, Vilayanur Viswanathan, Venkat R. Subramanian
Summary: This study proposes a model that describes the growth of the solid-electrolyte interphase (SEI) layer on the electrode surface as a moving interface. It considers the effects of lithium ions and solvent affected by this interface, and solves the equations that govern species transport and potential drop. The study finds that this potential has a significant impact on capacity fade of the battery.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2022)
Review
Electrochemistry
Graziano Di Donato, Tugce Ates, Henry Adenusi, Alberto Varzi, Maria Assunta Navarra, Stefano Passerini
Summary: This review discusses the role of electrolytes in Li-S batteries, focusing on the main issues and solutions for the shuttle mechanism of polysulfides and the instability of the interface with lithium metal.
BATTERIES & SUPERCAPS
(2022)
Article
Nanoscience & Nanotechnology
Yang Liu, Bryan R. Wygant, Oluwaniyi Mabayoie, Jie Lin, Kenta Kawashima, Jun-Hyuk Kim, Wenzhang Li, Jie Li, C. Buddie Mullins
ACS APPLIED MATERIALS & INTERFACES
(2018)
Article
Chemistry, Physical
Yang Liu, Bryan R. Wygant, Kenta Kawashima, Oluwaniyi Mabayoje, Tae Eun Hong, Sang-Geul Lee, Jie Lin, Jun-Hyuk Kim, Kunio Yubuta, Wenzhang Li, Jie Li, C. Buddie Mullins
APPLIED CATALYSIS B-ENVIRONMENTAL
(2019)
Article
Chemistry, Multidisciplinary
Jie Lin, Jin-Myoung Lim, Duck Hyun Youn, Yang Lin, Yuxin Cai, Kenta Kawashima, Jun-Hyuk Kim, Dong-Liang Peng, Hang Guo, Graeme Henkelman, Adam Heller, C. Buddie Mullins
Article
Nanoscience & Nanotechnology
Jie Lin, Hu Peng, Jun-Hyuk Kim, Bryan R. Wygant, Melissa L. Meyerson, Rodrigo Rodriguez, Yang Liu, Kenta Kawashima, Dandan Gu, Dong-Liang Peng, Hang Guo, Adam Heller, C. Buddie Mullins
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Chemistry, Multidisciplinary
Qian Wang, Wei He, Laisen Wang, Shuai Li, Hongfei Zheng, Qun Liu, Yuxin Cai, Jie Lin, Qingshui Xie, Dong-Liang Peng
Summary: The study introduces sodium citrate as a chelating agent to synthesize lithium-rich manganese (LRM) based cathode materials with high structure stability, effectively controlling the morphology of the cathode materials and benefiting Li+ diffusion. The doping of Na+ helps to prevent structure collapse during repeated charge-discharge cycles, greatly enhancing voltage stability and improving lithium storage performance. The novel strategy of morphology design and Na+ doping synergistically increases the rate capacity and voltage retention of LRM cathode materials.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2021)
Article
Nanoscience & Nanotechnology
Qiulin Chen, Hao Li, Melissa L. Meyerson, Rodrigo Rodriguez, Kenta Kawashima, Jason A. Weeks, Hohyun Sun, Qingshui Xie, Jie Lin, Graeme Henkelman, Adam Heller, Dong-Liang Peng, C. Buddie Mullins
Summary: By depositing a LiZn alloy layer on the surface of Li foil, this study successfully protected and improved the Li metal anode, leading to longer cycling life and increased Coulombic efficiency.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Review
Materials Science, Multidisciplinary
Wei He, Qing-Shui Xie, Jie Lin, Bai-Hua Qu, Lai-Sen Wang, Dong-Liang Peng
Summary: In this article, the structure controversy and phase transition mechanisms of Li- and Mn-rich cathode materials are summarized. The causes of initiating or accelerating phase transition are summarized into three main driving forces, and the applications of phase transition behavior in improving the electrochemical performance are discussed.
Article
Chemistry, Physical
Yan Li, Guangyu Chen, Jie Lin, Liuqing Huang, Chentong Zhang, Xuetao Luo
Summary: The Si@C/TiO2@C/Hollow-C anode materials prepared by mixing and carbonizing SiNPs and TC4NPs in different proportions provide ample space for the volume expansion of silicon while reducing transfer impedance. The anatase TiO2 in TC4NPs helps relieve volume expansion and enhance electrical conductivity during charge/discharge, leading to excellent rate performance and 92% reversible capacity retention after cycling at higher current densities.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Nanoscience & Nanotechnology
Yanli Chen, Jiaqi Ma, Qiong Peng, Xiu Gong, Jie Lin, Xiaosi Qi, Hang Guo
Summary: In this study, tin oxide/carbon composites with a metaphosphate-bridged interface were synthesized to improve the interfacial contact between tin oxides and carbon, thereby enhancing lithium-storage performance. The formation of the metaphosphate-bridged interface provided a steady transport channel, enhanced charge transfer and interaction, leading to higher SnOx utilization.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Liang Lin, Fang Liu, Yinggan Zhang, Chengzhi Ke, Hongfei Zheng, Fangjun Ye, Xiaolin Yan, Jie Lin, Baisheng Sa, Laisen Wang, Dong-Liang Peng, Qingshui Xie
Summary: A mixed ionic and electronic conductive (MIEC) interphase layer with an adjustable ratio assembled by ZnO and Zn nanoparticles is developed to achieve optimized interface kinetics, improving the cycling stability and capacity retention of lithium metal batteries.
Article
Chemistry, Multidisciplinary
Jie Lin, Laisen Wang, Qingshui Xie, Qing Luo, Dong-Liang Peng, C. Buddie Mullins, Adam Heller
Summary: Passivation of stainless steel by additives forming mass-transport blocking layers is extended to Si anodes for lithium-ion batteries, incorporating the passivator of LiF/Li2CO3 into bulk Si. The passivation mechanism is studied and it is found to enhance the (de)lithiation of Li-Si alloys, induce the formation of F-rich solid electrolyte interphase, stabilize the Si/LiF/Li2CO3 composite, and mitigate the volume change of Si anodes. The 3D passivated Si anode shows excellent cycling stability and high rate capability.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Review
Materials Science, Multidisciplinary
Jie Lin, Liang Lin, Shasha Qu, Dongyuan Deng, Yunfan Wu, Xiaolin Yan, Qingshui Xie, Laisen Wang, Dong-Liang Peng
Summary: All-solid-state thin-film lithium batteries (TFLBs) are considered as the ideal wireless power sources for on-chip micro/nanodevices due to their significant advantages of safety, portability, and integration. Despite the ongoing improvements in key components like cathode, electrolyte, and anode to increase energy density, challenges and strategies from the latest materials developed for lithium-ion batteries (LIBs) are being leveraged for TFLBs. Recent advances in TFLBs have focused on meeting high-energy density and long-term durability demands through advanced manufacturing and characterization techniques.
ENERGY & ENVIRONMENTAL MATERIALS
(2022)
Article
Chemistry, Physical
Kenta Kawashima, Kihyun Shin, Bryan R. Wygant, Jun-Hyuk Kim, Chi L. Cao, Jie Lin, Yoon Jun Son, Yang Liu, Graeme Henkelman, C. Buddie Mullins
ACS APPLIED ENERGY MATERIALS
(2020)
Article
Chemistry, Physical
Jie Zhang, Jie Lin, Yibo Zeng, Ying Zhang, Hang Guo
ACS APPLIED ENERGY MATERIALS
(2019)
Article
Chemistry, Physical
Kenta Kawashima, Yang Liu, Jun-Hyuk Kim, Bryan R. Wygant, Isabelle Cheng, Hugo Celio, Oluwaniyi Mabayoje, Jie Lin, C. Buddie Mullins
ACS APPLIED ENERGY MATERIALS
(2019)
Article
Chemistry, Physical
Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu
Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen
Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu
Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing
Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen
Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang
Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo
Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu
Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas
Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov
Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei
Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur
Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea
Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang
Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu
Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.
JOURNAL OF POWER SOURCES
(2024)