Article
Chemistry, Physical
L. Bouleau, S. Perez-Rodriguez, J. Quilez-Bermejo, M. T. Izquierdo, F. Xu, V. Fierro, A. Celzard
Summary: This study investigates the ORR performance of porous carbon materials and optimizes different key factors. The results indicate that individual optimization of experimental conditions should be conducted for each material, and important benchmarks for evaluating the catalytic activity of carbon-based catalysts in ORR are provided.
Review
Chemistry, Physical
Saswati Santra, Verena Streibel, Ian D. Sharp
Summary: The transition from a global economy dependent on fossil fuels to one based on sustainable energy conversion technologies is the primary challenge of the day. Earth-abundant bifunctional transition metal catalysts, especially those based on molybdenum (Mo), show great promise in reducing cost, simplifying systems, and providing prospects for accelerated scaling and sustainable material reuse. This comprehensive review focuses on recent progress in Mo-based multifunctional catalysts, discussing various formations and structures, as well as emerging trends and opportunities in this promising materials space.
Article
Nanoscience & Nanotechnology
Tuan Sang Tran, Rajkamal Balu, Chung Kim Nguyen, Jitendra Mata, Vi Khanh Truong, Naba Kumar Dutta, Namita Roy Choudhury
Summary: A solution-processable graphene-based electrocatalyst for the oxygen reduction reaction (ORR) is developed using a facile liquid-phase exfoliation process. The interfacial interaction between poly(3-hexylthiophene-2,5-diyl) (P3HT) nanoparticles and graphene stabilizes the exfoliated graphene flakes and induces efficient intermolecular charge transfer, accelerating the ORR. This printable graphene electrocatalyst provides a breakthrough in low-cost and sustainable fuel cell fabrication.
ACS APPLIED NANO MATERIALS
(2023)
Article
Engineering, Environmental
Amit Chaturvedi, Patit Paban Kundu
Summary: Microbial fuel cell technology utilizes organic substrates and oxygen to generate power, with the performance relying on the catalysts used for the oxygen reduction reaction. Various types of catalysts, including electrocatalysts, photo-electrocatalysts, and biocatalysts, have been evaluated for their electrochemical properties, catalytic effectiveness, stability, and power generation in MFCs.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Green & Sustainable Science & Technology
Sachin Kumar, Athira Yoyakki, Ajmal Pandikassala, Roby Soni, Sreekumar Kurungot
Summary: Commercially available Pt/C catalysts used in PEMFCs suffer from insufficient triple-phase boundary formation and carbon oxidation, leading to shortened lifetime and efficiency. To address this issue, a new class of carbon-free electrocatalysts was developed by dispersing Pt nanoparticles on ZrP nanoplates. The Pt/ZrP electrocatalyst showed improved durability and 4.6 times higher mass activity compared to Pt/C. Single-cell level validation demonstrated achievable current densities of 0.600, 0.890, and 0.890 A cm(-2) for ZrP@Pt, Pt/ZrP, and Pt/C, respectively, in PEMFC.
ADVANCED SUSTAINABLE SYSTEMS
(2023)
Article
Chemistry, Physical
Yuanyuan Zheng, Amanda Schramm Petersen, Hao Wan, Rene Huebner, Jiangwei Zhang, Jianlan Wang, Haoyuan Qi, Yuhong Ye, Chaolun Liang, Jing Yang, Zhiming Cui, Yuezhong Meng, Zhikun Zheng, Jan Rossmeisl, Wei Liu
Summary: A scalable, controllable, and general strategy to prepare Pt-based oxygen reduction reaction (ORR) electrocatalysts with excellent performance and stability was demonstrated. The Pt83Ni17 bunched-nanocages aerogels (BNCs AG) showed significantly enhanced ORR activity and durability compared to Pt/C, with mass activity (MA) of 1.95 A mg(Pt)(-1) and MA retention of 82.6% after a 20,000-cycles accelerated durability test. The optimized ligand and strain effects, as well as the appropriate porosity, contributed to the excellent activity and durability of the Pt83Ni17 BNCs AG.
ADVANCED ENERGY MATERIALS
(2023)
Article
Green & Sustainable Science & Technology
Pranav K. Gangadharan, Vidyanand Vijayakumar, Shijil A. Nediyirakkal, Roshni Tresa Fernandez, Adhrika Siddharthan, Sreekumar Kurungot
Summary: A high-performance electrocatalyst Pt/3DNG for PEMFC applications has been developed by grafting an active triple-phase boundary on the 3DNG support material to precisely control the formation of the proton conducting ionomer interface at the active sites. Introducing the concept of in situ generation of the proton conducting-ionomer based active triple-phase boundary during electrode fabrication could potentially replace the conventional method of using Nafion ionomer for electrode preparation.
ADVANCED SUSTAINABLE SYSTEMS
(2021)
Review
Energy & Fuels
Maryam Jafari, Mohammad Javad Parnian, Hussein Gharibi, Zibin Liang, Ruqiang Zou
Summary: This review article focuses on the clarification of the synthesis-structure-activity correlations of ORR electrocatalysts for fuel cell applications. It discusses the classification of different MOF precursors and their final desirable electrocatalysts after the pyrolysis process. The investigation includes ORR performance and fuel cell performances of various MOF-derived materials, providing readers with a deeper understanding of nonprecious MOF-derived catalysts in the emerging field.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Review
Electrochemistry
Shiming Zhang, Menghui Chen, Xiao Zhao, Jialin Cai, Wei Yan, Joey Chung Yen, Shengli Chen, Yan Yu, Jiujun Zhang
Summary: This review provides a comprehensive overview and in-depth analysis of recent progress in noncarbon materials for ORR electrocatalysts, discussing their advantages and drawbacks, as well as proposing strategies to enhance electrocatalytic performance.
ELECTROCHEMICAL ENERGY REVIEWS
(2021)
Article
Chemistry, Inorganic & Nuclear
Ijaz Ur Rehman, Jie Zhang, Jinwei Chen, Ruilin Wang
Summary: Metal-organic-framework derived carbon-based nanomaterials have attracted significant interest due to their remarkable electrocatalytic activity, affordable cost, and exceptional stability. In this study, efficient Ni-N-CNTs catalysts were prepared by pyrolysis and exhibited excellent oxygen reduction reaction (ORR) performance and stability in alkaline medium.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Bo Wei, Zhongheng Fu, Dominik Legut, Timothy C. Germann, Shiyu Du, Haijun Zhang, Joseph S. Francisco, Ruifeng Zhang
Summary: Designing highly active and bifunctional oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts with non-noble metals such as Fe/Co/Ni on MXene surfaces has shown superior performance compared to traditional unifunctional catalysts, providing a novel pathway for tunable catalytic behavior in MXenes. The electronic structure analyses revealed that the excellent catalytic activities in MXene-based DACs are attributed to the electron-capturing capability and synergistic interactions between Fe/Co/Ni adsorbents and MXene substrate. These findings not only suggest promising candidates for MXene-based bifunctional ORR/OER catalysts but also offer new theoretical insights into rationally designing noble-metal-free bifunctional DACs.
ADVANCED MATERIALS
(2021)
Review
Chemistry, Physical
Shengnan Li, Shih-Hsin Ho, Tao Hua, Qixing Zhou, Fengxiang Li, Jingchun Tang
Summary: Microbial fuel cells (MFCs) as a novel wastewater treatment that generates electricity has received significant attention, but the low activity of the oxygen reduction reaction (ORR) remains a critical bottleneck. Biochar has been considered as a promising ORR electrocatalyst, with further research needed to improve its economic practicality. The review covers the ORR mechanism, essential requirements of ORR catalysts in MFC applications, material selection, properties, preparation of biochar electrocatalysts, and specific applications in MFCs, highlighting challenges and future research directions.
GREEN ENERGY & ENVIRONMENT
(2021)
Article
Nanoscience & Nanotechnology
Liyang Wan, Weikun Chen, Hui Xu, Yucheng Wang, Jiayin Yuan, Zhiyou Zhou, Shigang Sun
Summary: This study utilized a CO2 etching method to flexibly tailor the pore structure of Fe/N/C electrocatalysts, revealing the impact of pore structure on ORR activity. A high-quality electrocatalyst was developed with polarization performance exceeding that of commercial Pt/C catalyst.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Kun Wang, Hui Chai, Yali Cao
Summary: A facile strategy of synthesizing hierarchical CoNx/Co@NC electrocatalyst with abundant edge defects is reported in this study. The introduction of edge defects not only improves the catalytic activity, but also optimizes the electronic structure, resulting in superior electrocatalytic performance.
Review
Chemistry, Physical
Suranjana Patowary, Rashmi Chetry, Chiranjita Goswami, Bhugendra Chutia, Pankaj Bharali
Summary: This article primarily documents the recent advancements and challenges of supported nanomaterials with fascinating properties towards oxygen reduction reaction (ORR). The use of carbon-based materials as support and the significant factors affecting ORR activity are discussed, along with the electrochemical techniques and parameters used for data collection and evaluation.
Article
Energy & Fuels
Shiyou Yang, Quande Wang, Henry J. Curran, Ming Jia
Summary: A 5-component gasoline surrogate chemical kinetic mechanism has been developed and validated in this study, featuring detailed and improved sub-mechanisms for accurate simulation of combustion processes in gasoline engines. The prediction accuracy of the mechanism remains within 5% for various fuel blends under different operating conditions, confirming its feasibility for CFD simulations. Through optimization of reaction rate constants to match experimental data, the mechanism shows promising potential in combustion, emissions, and knock studies.
Article
Chemistry, Physical
Quan-De Wang, Mao-Mao Sun, Jinhu Liang
Summary: This study systematically investigates the hydrogen abstraction reactions from different substituted phenolic compounds in bio-oils, revealing the effects of the aromatic ring and side-chain substituent on hydrogen abstractions.
COMPUTATIONAL AND THEORETICAL CHEMISTRY
(2021)
Article
Energy & Fuels
Quan-De Wang, Snehasish Panigrahy, Shiyou Yang, Sergio Martinez, Jinhu Liang, Henry J. Curran
Summary: This communication presents efficient skeletal core combustion mechanisms for small C-0-C-4 fuel molecules using NUIGMech1.1. The skeletal mechanisms have been validated and can be utilized in the development of a five-component skeletal mechanism for real gasoline.
Article
Energy & Fuels
Zhi-Yuan Yang, Ping Zeng, Bi-Yao Wang, Wenlin Jia, Zu-Xi Xia, Jinhu Liang, Quan-De Wang
Summary: This study experimentally investigated the autoignition characteristics of jet fuel from direct coal liquefaction and its blends with conventional RP-3 jet fuel. The research explored the effects of temperature, pressure, and equivalence ratio on ignition delay times, developed surrogate models and detailed kinetic mechanism for combustion chemistry, and conducted brute force sensitivity analyses to identify key reactions controlling ignition characteristics. The results provide valuable insights into the ignition properties of alternative jet fuels.
Article
Energy & Fuels
Jinhu Liang, Xiaoliang Li, Fei Li, Bi-Yao Wang, Ping Zeng, Zhi-Yuan Yang, Zu-Xi Xia, Quan-De Wang
Summary: This study systematically evaluates the sooting characteristics of alternative jet fuels produced from DCL, obtaining soot induction time and yield through experiments. The effects of temperature, pressure, and equivalence ratio on soot characteristics are analyzed, providing valuable data for combustion kinetic model development and airworthiness certification process.
Article
Nanoscience & Nanotechnology
Shang-Bo Li, Ling Liu, Yu-Jie Zhang, Zhi-Qiang Xia, Ning Wang, Quan-De Wang
Summary: The study successfully constructed double-shelled NiCo-LDH@MSiO3 hollow polyhedral cages with high adsorption capacity, with a maximum adsorption capacity of 510.6 mg/g for Congo red, indicating a high efficiency for removal of Congo red from aqueous solution and potential application in water treatment.
Article
Chemistry, Multidisciplinary
Shenying Xu, Jinhu Liang, Shutong Cao, Ruining He, Guoliang Yin, Quan-De Wang
Summary: The abstraction of hydrogen atom by methyl peroxy radical is a crucial reaction class in studying the autoignition properties of hydrocarbon fuels. Theoretical calculations were performed to determine the rate constants for this reaction class in H-2/C-1-C-4 fuels and the results were applied in the development of a base model for large fuels.
Article
Thermodynamics
Dao Zheng, Dong He, Quan-De Wang, Yanjun Ding, Zhimin Peng
Summary: This study measured the temperature, CO, and CO2 time-histories for the oxidation of n-heptane/diethyl ether/O2/argon mixtures and developed a kinetic model for prediction and analysis. The predictions based on different mechanisms showed different accuracies for different conditions and blending ratios, indicating the need for further improvements.
COMBUSTION AND FLAME
(2022)
Article
Chemistry, Multidisciplinary
Jinhu Liang, Fei Li, Shutong Cao, Xiaoliang Li, Ruining He, Ming-Xu Jia, Quan-De Wang
Summary: An experimental and kinetic modeling study of the high-temperature ignition of cyclohexene is performed, showing that the ignition delay time varies with temperature, equivalence ratio, and pressure. Different detailed kinetic mechanisms exhibit significant differences, and there are still no unified conclusions about the major reaction path for cyclohexene oxidation.
Article
Engineering, Multidisciplinary
Jin-hu Liang, Shu-tong Cao, Fei Li, Xiao-liang Li, Rui-ning He, Xin Bai, Quan-De Wang, Yang Li
Summary: The pyrolysis of cyclohexane, methylcyclohexane, and ethylcyclohexane at pressures of 5 and 10 bar and temperatures of 930-1550 K was studied using reflected shock waves. Pyrolysis experiments were performed in a single-pulse shock tube with reaction times ranging from 1.65 to 1.74 ms. Gas chromatography analysis was used to obtain and quantify major products. Kinetic modeling was conducted using detailed and lumped chemical kinetic mechanisms. Reaction path analysis and sensitivity analysis were performed to determine the important reactions controlling fuel pyrolysis and their impact on species concentrations. This study provides new fundamental knowledge and data for developing detailed kinetic mechanisms.
DEFENCE TECHNOLOGY
(2023)
Article
Energy & Fuels
Jinhu Liang, Fei Li, Shutong Cao, Xiaoliang Li, Ming-Xu Jia, Quan-De Wang
Summary: This study presents a comparative experimental and kinetic modeling investigation of high-temperature ignition of three C9H12 fuels. The results provide valuable data and insights into the ignition delay time and chemical kinetics, contributing to the understanding and modeling of alkyl aromatics' combustion chemistry.
Article
Chemistry, Physical
Ming-Xu Jia, Quan-De Wang, Xue-Feng Ren, Guo-Jun Kang
Summary: The thermochemistry properties of C/H/O/N compounds are essential for understanding the reactivity and safety of energetic materials. This study employs various composite methods to calculate bond dissociation energies and enthalpies of formation of C/H/O/N species with sufficient chemical diversity. The performance of these methods is analyzed systematically, along with the structural effect on the thermochemistry properties of the studied species. This research provides valuable information for selecting composite methods in C/H/O/N systems and contributes to the foundation of synthesizing energetic materials.
CHEMICAL PHYSICS LETTERS
(2023)
Article
Thermodynamics
Jinhu Liang, Chen Zhao, Ziwen Zhao, Xinhui Wang, Ming-Xu Jia, Quan-De Wang, Yang Zhang, Fengqi Zhao
Summary: This study investigates the high-temperature ignition and pyrolysis characteristics of cyclohexylamine through experimental and kinetic modeling approaches. The results show that the ignition delay times and pyrolysis product distributions of cyclohexylamine are influenced by temperature, pressure, and equivalence ratio. A detailed kinetic mechanism accurately predicts the experimental results. Sensitivity analysis identifies the most sensitive reaction as O2 + H = O + OH, and the abstraction reaction of cyclohexylamine with OH radical also exhibits significant sensitivity coefficients. Reaction path analysis reveals the control role of abstraction reactions in the initial oxidation of cyclohexylamine.
COMBUSTION AND FLAME
(2023)
Article
Engineering, Environmental
Fei Huang, Zhen Li, Yifeng Xu, Aihua Yan, Tongyang Zhang, Quande Wang, Shihang Li, Shijian Lu, Wenxue Zhao, Ye Gao, Jixu Zhang
Summary: In this study, a p-n-n-type Ni(OH)(2)/NiIn2S4/ZnIn2S4 heterojunction was constructed to overcome the bottleneck problem of sluggish elimination of photogenerated holes in photocatalytic water splitting system. This heterojunction exhibited excellent visible-light-driven hydrogen production performance and enhanced anti-photocorrosion and long-term stability.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Thermodynamics
Quan-De Wang, Yanjin Sun, Ziwen Zhao, Yang Zhang, Fengqi Zhao, Yang Li, Jinhu Liang
Summary: In this study, the ignition kinetics of nitrocyclohexane in inert and air environments were investigated using a high-pressure shock tube facility. The experiments were conducted at various pressures, equivalence ratios, and temperatures. The effect of different fuel concentrations with nitrogen as the inert gas was also studied. Comparisons with other fuels were made to understand the combustion chemistry of nitroalkanes. This study provides valuable experimental data for nitroalkanes in inert conditions and contributes to the understanding of their combustion chemistry.
COMBUSTION AND FLAME
(2023)
Article
Chemistry, Physical
Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu
Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen
Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu
Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing
Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen
Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang
Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo
Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu
Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas
Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov
Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei
Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur
Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea
Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang
Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu
Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.
JOURNAL OF POWER SOURCES
(2024)