4.8 Article

Novel As-doped, As and N-codoped carbon nanotubes as highly active and durable electrocatalysts for O2 reduction in alkaline medium

期刊

JOURNAL OF POWER SOURCES
卷 306, 期 -, 页码 535-540

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2015.12.053

关键词

Arsenic-containing carbon nanotubes; Metal-free electrocatalysts; Oxygen reduction reaction; Fuel cells

资金

  1. National Natural Science Foundation of China [21376257]
  2. Jiangsu Provincial Natural Science Foundation of China [BK20131112]

向作者/读者索取更多资源

To develop more efficient metal-free cathode electrocatalysts for fuel cells, novel arsenic (As)-doped, As and N-codoped carbon nanotubes are synthesized by chemical vapor deposition in this work. The as prepared As-containing carbon nanotubes exhibit significantly enhanced activity and long-term durability for the oxygen reduction reaction (ORR) in alkaline medium, indicating that the doping of As or codoping As with other heteroatoms into carbon matrix could improve the ORR activity of carbon materials due to the changes in electronic and physical properties of carbon nanotubes evidenced by density functional theory calculations. Moreover, As-containing carbon nanotubes also display much better methanol tolerance, showing a good potential application for future fuel cells. (C) 2015 Elsevier B.V. All rights reserved.

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