期刊
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS
卷 49, 期 23, 页码 -出版社
IOP Publishing Ltd
DOI: 10.1088/0953-4075/49/23/235201
关键词
state-changing collision; quantum scattering calculations; rotational cooling in ion traps; ion-molecule inelastic scattering
资金
- FWF Austrian Science Fund [P27047-N20]
- Spanish Ministry of Science and Innovation [CTQ2012-37404-C02-02]
- Austrian Science Fund (FWF) [P27047] Funding Source: Austrian Science Fund (FWF)
We report in the present study a quantum analysis of the collisional dynamics involving a negative ion, LiH- in its (2)Sigma(+) ground electronic state, and He as a buffer gas in the environment of cold ion traps. The work focuses on the evaluation of the internal cooling collisional rates, treating both the anion's rotational quantum numbers and the spin-changing processes. The calculations are carried out over a range of energies capable of yielding the corresponding rates for state-changing events over a rather broad interval of temperatures, thus covering those usually reached in the cold traps experiments and even beyond to lower temperatures.
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