Long-term impacts of impervious surface cover change and roadway deicing agent application on chloride concentrations in exurban and suburban watersheds

Roadway deicing agents, including rock salt and brine containing NaCl, have had a profound impact on the water quality and aquatic health of rivers and streams in urbanized areas with temperate climates. Yet, few studies evaluate im-pacts to watersheds characterized by relatively low impervious surface cover (ISC; < 15 %). Here, we use long-term (1997-2019), monthly streamwater quality data combined with daily streamflow for six exurban and suburban water-sheds in southeastern Pennsylvania to examine the relations among chloride (Cl-) concentrations and ISC. Both flow -normalized Cl(-)concentrations and ISC increased over time in each of the six watersheds, consistent with changes in watershed management (e.g., ISC, road salt application, etc.). The watersheds that experienced the greatest changes in percent ISC (e.g., agriculture replaced by residential and commercial development) experienced the greatest changes in flow-normalized Cl- concentrations. We also utilized a comprehensive mass-balance model (2011-2018) that indicated C-- inputs exceeded the outputs for the study watersheds. Road salt applied to state roads, non-state roads, and other impervious surfaces accounted for the majority of Cl- inputs to the six watersheds. Furthermore, increasing Cl- concentrations during baseflow conditions confirm impacts to shallow groundwater. Although flow-normalized Cl- concentrations are below the U.S. Environmental Protection Agency's chronic threshold value for impacts to aquatic organisms, year-round exceedances may result before the end of this century based on current trends. Though reduced Cl- loading to streams maybe achieved by limiting the expansion of impervious surfaces in exurban and suburban watersheds, changes in baseflow concentrations are likely to be gradual because of the accumulated C- in groundwater.

Automated summary

Roadway deicing agents, such as rock salt and brine, have had a significant impact on the water quality and aquatic health in urban areas. This study examines the effects of chloride concentrations and impervious surface cover in six watersheds in Pennsylvania. The results show that both chloride concentrations and impervious surface cover have increased over time, with the greatest changes observed in watersheds that experienced changes in land use. The study also highlights the importance of road salt application in contributing to chloride inputs in the watersheds. Although current chloride concentrations are below the threshold for impacts on aquatic organisms, there is a likelihood of exceedances in the future. Limiting the expansion of impervious surfaces can help reduce chloride loading to streams, but changes in baseflow concentrations may be gradual due to accumulated chloride in groundwater.