期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 120, 期 10, 页码 5503-5514出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.5b12010
关键词
-
资金
- Ministry of Science and Technology of China [2013CB834605]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB01020100]
- National Natural Science Foundation of China [91321309, 91421313, 51132007, 21421063, 21573207]
We systematically investigated the photocatalytic reaction of methanol on the TiO2 (110)-(1 x 1) surface under irradiation with ultraviolet (UV) light performed at various conditions, using scanning tunneling microscopy (STM) jointed with temperature-programmed desorption (TPD) techniques. Our STM and TPD results show that the photocatalytic reaction is indeed initiated from the molecular methanol at the S-fold coordinated Ti sites, as commonly ascribed to the methanol oxidation by the photogenerated holes, reflecting the highly photoactive nature of methanol. The formaldehyde yield from the TPD results is much smaller by a factor of 2/3 than the amount of dissociated methanol from the STM results at 80 K. This observation can be assigned to the reverse reaction during the TPD measurement, and may explain the lower yield of formaldehyde using molecular methanol than using methoxy. From the fractal-like reaction kinetics of methanol, we can associate the coverage-dependence of the spectral dimensions with the change for the diffusion of holes across the surface from a one-dimensional to a two-dimensional behavior because of the increased scattering species at higher coverages. Our results here provide a clear picture for the photocatalytic reaction of molecular methanol and may rationalize the different observations performed at various conditions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据