Article
Chemistry, Physical
Okkyun Seo, Jaemyung Kim, Jiayi Tang, L. S. R. Kumara, Koji Kimoto, Kazushi Miki, Akifumi Matsuda, Mamoru Yoshimoto, Osami Sakata
Summary: This research focuses on the influence of atomic arrangement on the electrical and catalytic properties of oxide thin films. The atomic arrangement of LiNiO2 thin films was investigated by uniaxial compression and annealing at 600℃ on sapphire substrates. Thin films with a rock-salt structure were grown using pulsed laser deposition method at room temperature. It was observed that the as-grown thin films transformed from a rock-salt to a layered structure after uniaxial compression at 600℃, and the layer thickness of the latter structure increased with increasing uniaxial compression pressure. Uniaxial compression provides a useful tool for oxide thin film research, contributing to the development of new functional oxide materials and adjustment of the atomic ordering of cation materials.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
T. Roch, M. Gregor, S. Volkov, M. Caplovicova, L. Satrapinskyy, A. Plecenik
Summary: This study examined the impact of different substrates on the structure and orientation of niobium nitride thin films, revealing that films on C-Al2O3 substrate exhibited the best superconducting properties.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Arun Kumar Mukhopadhyay, Avishek Roy, Gourab Bhattacharjee, Sadhan Chandra Das, Abhijit Majumdar, Harm Wulff, Rainer Hippler
Summary: The surface stoichiometry of Tix-CuyNz thin film was investigated as a function of film depth using high power impulse and DC magnetron sputtering. X-ray photoelectron spectroscopy revealed the composition of Ti, Cu, and N in the deposited film. The presence of Cu3N and Ti3CuN phases in the film was confirmed by grazing incidence X-ray diffraction and transmission electron microscopy, respectively.
Article
Materials Science, Multidisciplinary
Niklas Wolff, Philipp Jordt, Justin Jetter, Henning Vogt, Andriy Lotnyk, Klaus Seemann, Sven Ulrich, Eckhard Quandt, Bridget M. Murphy, Lorenz Kienle
Summary: Composites of ultra-thin nanolayers of FeCo/TiN exhibit stability at high temperatures and defined magnetic properties that can be tuned by adjusting layer thickness. Using aberration-corrected microscopes and X-ray diffraction analysis, the nanostructure was found to consist of individual layers of FeCo and TiN forming a superlattice with a specific orientation relationship. Simulation of electron diffraction patterns confirmed a defined orientation relationship leading to the stabilization of tetragonal FeCo unit cells at the nanoscale.
MATERIALS CHARACTERIZATION
(2021)
Article
Crystallography
Kaito Tsuboi, Nan Su, Shotaro Kobayashi, Kota Sugimoto, Masakazu Kobayashi
Summary: In this study, SnTe thin films were grown on GaAs substrates using molecular beam epitaxy. Stoichiometric SnTe layers were achieved by adjusting the molecular beam intensity ratio and substrate temperature. Excess Te was found to remain in the films when the molecular beam intensity ratio was Te rich. The formation of continuous films and the segregation of Te in certain samples were confirmed.
JOURNAL OF CRYSTAL GROWTH
(2022)
Article
Nanoscience & Nanotechnology
Paola Di Pietro, Chiara Bigi, Sandeep Kumar Chaluvadi, Daniel Knez, Piu Rajak, Regina Ciancio, Jun Fujii, Francesco Mercuri, Stefano Lupi, Giorgio Rossi, Francesco Borgatti, Andrea Perucchi, Pasquale Orgiani
Summary: The occurrence of oxygen-driven metal-insulator-transition (MIT) in SrNbO3 thin films grown on DyScO3 has been studied. The results show that increasing oxygen content leads to vertical shrinkage of the SNO unit cell while maintaining epitaxial matching with the substrate. Highly oxygenated films exhibit distinct insulating behavior compared to oxygen deficient films. Tailoring the optical absorption and conductivity across the MIT in strontium niobate epitaxial films will have potential applications.
ADVANCED ELECTRONIC MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Alberto Binetti, Wei-Fan Hsu, Koen Schouteden, Jin Won Seo, Jean-Pierre Locquet, Maria Recaman Payo
Summary: Vanadium sesquioxide (V2O3) is a promising material for new-generation sensors or smart devices due to its strong correlation effects and tunable metal-insulator transitions. The successful growth of epitaxial thin films on silicon substrates has been achieved by adjusting the growth conditions, and extensive characterization has been carried out. Structural analysis reveals the impact of temperature on thin film microstructures, and the lattice mismatch between silicon and V2O3 induces the growth of the corundum PI phase. Additionally, small deviations from stoichiometry significantly affect the resistivity change upon cooling.
RESULTS IN PHYSICS
(2023)
Article
Materials Science, Multidisciplinary
Aaron J. McLeod, Scott T. Ueda, Ping C. Lee, Jeff Spiegelman, Ravindra Kanjolia, Mansour Moinpour, Jacob Woodruff, Andrew C. Kummel
Summary: In this study, low temperature AlN deposition was achieved on Si(100), Si(111), and 4H-SiC substrates using a metal precursor with high thermal stability and a highly reactive nitrogen source. Two different processes, a 580°C pulsed chemical vapor deposition (CVD) and a more complex 400°C atomic layer annealing process, were compared. Both processes showed comparable enhancement in crystallinity of the subsequently sputtered AlN films.
Article
Nanoscience & Nanotechnology
Alexander Vogel, Alicia Ruiz Caridad, Johanna Nordlander, Martin F. Sarott, Quintin N. Meier, Rolf Erni, Nicola A. Spaldin, Morgan Trassin, Marta D. Rossell
Summary: Recent studies have found that oxygen defects on the surface of improper ferroelectric thin films can result in the loss of ferroelectric response. We investigated hexagonal YMnO3 thin films and discovered that the polarization suppression in thinner films is due to oxygen vacancies. We demonstrated that these vacancies form on the film surfaces to screen the large internal electric field. Furthermore, by modifying the oxygen concentration, we can significantly tune the phase transition temperatures. These findings are expected to be applicable to other ferroelectric oxide films, highlighting the importance of controlling oxygen content and cation oxidation states for successful integration in nanoscale applications.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Nanoscience & Nanotechnology
G. De Luca, J. Spring, U. Bashir, M. Campanini, R. Totani, C. Dominguez, A. Zakharova, M. Dobeli, T. Greber, M. D. Rossell, C. Piamonteze, M. Gibert
Summary: The study shows that LNMO thin films maintain insulating behavior and a stable Curie temperature, regardless of the epitaxial strain conditions. This suggests that this material could be used in multi-layer device architectures that require a high-temperature ferromagnetic insulating state.
Article
Chemistry, Physical
Masaki Tahara, Kazuya Hasunuma, Hideki Hosoda
Summary: This study investigated the decomposition process of the isothermal alpha '' phase in beta-Ti alloys, and found that the resulting alpha + beta dual phase inherited the microstructural characteristics of the alpha ''(iso) phase. The research results indicate the existence of a strict variant selection rule between the decomposed alpha and beta phases, with a specific variant combination observed.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Materials Science, Ceramics
Khan Alam, Mohammad B. Haider, Mohammad F. Al-Kuhaili, Khalil A. Ziq, Bakhtiar Ul Haq
Summary: Chromium nitride thin films were prepared by reactive radio frequency magnetron sputtering, and their properties were studied in relation to the nitrogen to argon flow rate ratio and film composition. The results show that the film composition, band gap, and electronic phase transition are influenced by the gas flow ratio and film composition.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Multidisciplinary
Zhe Chuan Feng, Hao-Hsiung Lin, Bin Xin, Shi-Jane Tsai, Vishal Saravade, Jeffrey Yiin, Benjamin Klein, Ian T. Ferguson
Summary: The hetero-epitaxy of 3C-SiC on Si-face and C-face 4H-SiC was experimentally investigated, and a corresponding growth model was identified. This study provides valuable insights for band-gap engineering and various applications of SiC.
Letter
Materials Science, Multidisciplinary
Md Dalim Mia, Brian C. Samuels, Jonathan Anderson, Sree Sourav Das, Ariful Haque, Ravi Droopad
Summary: (Ga1-xFex)(2)O-3 thin films were grown on (0001)-Al2O3 substrates with a partial O-2 pressure of 1.5 x 10(-6) torr and temperature of 700 degrees C by pulsed laser deposition. The incorporation of Fe into Ga2O3 expands the lattice constant and causes a transformation from the monoclinic phase to gamma phase for x >= 0.10, confirmed by X-ray diffraction and transmission electron microscopy. Surface analysis shows that Fe is also responsible for controlling the grains and the migration of adatoms with the increasing Fe concentration. Optical transmission measurements show that with increasing Fe content, the absorption edge moves toward longer wavelengths with no intermediate absorption.
MRS COMMUNICATIONS
(2022)
Article
Chemistry, Physical
M. R. Butaev, V. I. Kozlovsky, V. P. Martovitsky, Y. K. Skasyrsky, D. E. Sviridov
Summary: An investigation was conducted on the growth of CdS/ZnSe multi quantum well (MQW) heterostructures by metalorganic vapor-phase epitaxy (MOVPE), revealing changes in QW design during growth and observing a blueshift in emission line. Simulation of experimental X-ray diffraction curves showed changes in the average composition of QWs and the formation of type II band offsets.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Bowen Zhang, Xinwei Wang, Dengkui Wang, Jilong Tang, Xuan Fang, Dan Fang, Xiaohua Wang, Rui Chen, Tingchao He, Zhipeng Wei
JOURNAL OF PHYSICAL CHEMISTRY C
(2019)
Article
Materials Science, Multidisciplinary
Peng Du, Xuan Fang, Qian Gong, Jiaming Li, Xufeng Kou, Hongbin Zhao, Xiaohua Wang
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
(2019)
Article
Chemistry, Multidisciplinary
Xiaotian Zhu, Fengyuan Lin, Zhihong Zhang, Xue Chen, Hao Huang, Dengkui Wang, Jilong Tang, Xuan Fang, Dan Fang, Johnny C. Ho, Lei Liao, Zhipeng Wei
Review
Energy & Fuels
Chenhao Gao, Keyi Zhong, Xuan Fang, Dan Fang, Hongbin Zhao, Dengkui Wang, Bobo Li, Yingjiao Zhai, Xueying Chu, Jinhua Li, Xiaohua Wang
Summary: ZnO, a wide bandgap semiconductor, has shown remarkable progress in optoelectronic applications, particularly in photocatalysis and photodetection fields. The construction of various ZnO-based composite structures is essential for further enhancing the material's optoelectronic performance.
Article
Materials Science, Multidisciplinary
Bo-Wen Zhang, Dan Fang, Xuan Fang, Hong-Bin Zhao, Deng-Kui Wang, Jin-Hua Li, Xiao-Hua Wang, Dong-Bo Wang
Summary: The study utilized a fractional monolayer alloy method to grow InAsSb alloy, achieving interface engineering that effectively suppresses Auger recombination process in the superlattice by introducing localized states with higher activation energies. This improvement led to a detectable photoluminescence signal at 250K with a center wavelength of 9μm.
Article
Materials Science, Multidisciplinary
Dong Wang, Hua-Min Zhao, Li Guo, Long Zhang, Hong-Bin Zhao, Xuan Fang, Sheng Li, Gong Wang
Summary: In this study, a prickly-sphere-like CuO-Co3O4 composite material was prepared via a hydrothermal method for non-enzymatic electrochemical glucose detection, showing excellent sensing performance.
Review
Chemistry, Multidisciplinary
Bobo Li, Feng Tian, Xiangqian Cui, Boyuan Xiang, Hongbin Zhao, Haixi Zhang, Dengkui Wang, Jinhua Li, Xiaohua Wang, Xuan Fang, Mingxia Qiu, Dongbo Wang
Summary: Rare-earth metals, specifically lanthanide ions, have shown great potential as dopants in metal halide perovskite materials, improving their optical and electronic properties. These ions can enhance solar energy absorption, enable multi-color and white light emissions, and improve charge carrier transport efficiency.
Article
Crystallography
Li Yang, Dengkui Wang, Dan Fang, Hao Yan, Yingjiao Zhai, Xueying Chu, Jinhua Li, Xuan Fang
Summary: Strain engineering is used to design lateral heterojunctions (LHSs) based on arsenic and antimony, and their sensing properties to NO2 are studied. The results show that the As/Sb LHS with ZZ interface under -4% compression strain exhibits the best sensing properties. This work lays the foundation for the fabrication of high-performance NO2 gas sensors.
Article
Nanoscience & Nanotechnology
Ruxue Li, Zhipeng Wei, Xuan Fang, Yanbin Wang, Yongfeng Li, Dengkui Wang, Jilong Tang, Dan Fang, Xueying Chu, Bin Yao, Rui Chen, Xiaohua Wang
ACS APPLIED NANO MATERIALS
(2018)
Article
Chemistry, Multidisciplinary
Xuan Fang, Zhipeng Wei, Dan Fang, Xueying Chu, Jilong Tang, Dengkui Wang, Xinwei Wang, Jinhua Li, Yongfeng Li, Bin Yao, Xiaohua Wang, Rui Chen