期刊
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
卷 143, 期 -, 页码 1-7出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.petrol.2016.02.009
关键词
Shale; Specific surface area; Particle size; Temperature; TOC; Mineral composition
资金
- Key Program of National Natural Science Foundation of China [51534006]
- National Science Fund for Distinguished Young Scholars [51125019]
- National Natural Science Foundation of China [51304165]
Shales contain abundant organic matter, and have complex mineral composition and developed nano pores. Shale porosity has large surface area and a strong gas adsorption capacity. The specific surface area (SSA) of shales is an important factor for the adsorption of shale gas, while there are several factors which can affect the test results of SSA. In this study, shales collected from Longmaxi formation in the south of Sichuan Basin were taken as the research object. A set of testing methods were established for determining shale SSA through low-pressure N-2 adsorption-desorption method. Following this, the key factors affecting shale SSA were investigated. The results show that particle size of shale samples has little effect on the SSA, and the recommended particle size for SSA measurement is about 3 mm. After 3-h heating treatment at 200 degrees C, most of adsorbed water and part of the interlayer water of clay minerals are removed, and the tested SSA is highest. Therefore, the recommended optimum degassing temperature is 200 degrees C. The content of total organic carbon and the SSA have positive linear relationship. The quartz content and the SSA show a good positive correlation. No positive correlation is found between the SSA and other mineral components. The SSA is of great significance for the evaluation of shale gas resources potential. (C) 2016 Elsevier B.V. All rights reserved.
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