Mechanistic investigation on Ce addition in tuning recrystallization behavior and mechanical property of Mg alloy

Constructing bimodal grain structure is a promising approach to achieve the high strength-ductility synergy in Mg alloy. Formation of bimodal grain is closely related to the dynamic and/or static recrystallization process, which has not been fully understood in the typical Mg-RE based alloy. In this work, it is claimed for the first time that the minor Ce addition (similar to 0.3 wt%) into Mg matrix significantly promotes the pyramidal and non-basal dislocations at the early stage of extrusion, which consequently enhances the formation of sub-grain boundaries via the movement and recovery of pyramidal II-type dislocations. At this stage, fine sub-grain lamellae are widely observed predominantly due to the low migration rate of sub-grain boundary caused by the limited mobility of dislocations. At the later stage, the sub-grains continuously transform into dynamic recrystallized (DRXed) grains that have (1010) Taylor axis and also strong fiber texture, indicating substantial activation of pyramidal II-type dislocation. The low mobility of dislocations, accompanied with the solute drag from grain boundary (GB) segregation and pinning from nano-phases, cause a sluggish DRX process and thus a bimodal microstructure with ultra-fined DRXed grains, similar to 0.51 mu m. The resultant texture hardening and grain refinement hardening effects, originated from bimodal microstructure, result in a yield strength of similar to 352 MPa, which is exceptional in Mg-Ce dilute alloy. This work clarifies the critical role of Ce addition in tuning recrystallization behavior and mechanical property of magnesium, and can also shed light on designing the other high-performance Mg alloys. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Automated summary

Adding a small amount of Ce element in magnesium alloy can significantly promote the formation of pyramidal and non-basal dislocations, thereby enhancing the formation and recrystallization process of subgrain boundaries, resulting in a bimodal microstructure.