4.5 Article

Silk fibroin fibers-based shape memory membrane with Janus wettability for multitiered wearable protection

期刊

JOURNAL OF MATERIALS RESEARCH
卷 38, 期 3, 页码 633-643

出版社

SPRINGER HEIDELBERG
DOI: 10.1557/s43578-022-00805-w

关键词

Fiber membrane; Shape memory; Janus wettability; Air filtration; Antibacterial; Wearable protection

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Researchers have developed a fiber-based membrane with Janus wettability using alternating electrospinning-electrospraying technology, which can resist air pollution and inhibit bacteria proliferation. The membrane consists of silk fibroin nanofibers-substrate, polyurethane nanospheres-top layer, and in-situ grown silver nanoparticles middle layer, providing a self-cleaning physical barrier and a bio-barrier for sterilization. The membrane also has a high PM2.5 filtration efficiency of approximately 98.1%.
Realizing breathable shape memory fiber-based material with antibacterial and waterproof performances is important for multitiered wearable protection to address the increasing concerns of air pollution. Herein, using an alternating electrospinning-electrospraying technology, we develop a fiber-based membrane with Janus wettability based on a silk fibroin nanofibers-substrate (SFNFs), a polyurethane nanospheres-top layer (PUNSs), and a middle layer of PU nanofibers-mat with in-situ grown silver nanoparticles (PUNFs-AgNPs), which serves separately for skin contact, a self-cleaning physical barrier to resist external aerosol/bacteria (PM2.5 filtration efficiency similar to 98.1%), and a bio-barrier that can sterilize harmful particles and inhibit bacteria proliferation (> 95%). This breathable Janus film (SFNFs/PUNFs-AgNPs/PUNSs, SPAP) with an antibacterial filter shows shape memory stretchability enabled by the thermoplastic PU component, which is mechanically adaptive to human body for wearable protection. This work presents a breathable wearable material for air-filtration and anti-bacteria, promising for applications such as wound dressings, medical masks, protection suits, and multifunctional filters.

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