期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 23, 页码 11603-11611出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01820
关键词
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资金
- National Basic Research Program of China (973 Program) [2015CB856600]
- Natural Science Foundation of China [21472004, 21332002]
An efficient metal-free phosphorylation process based on a Sandmeyer-type transformation with arylamines as the starting materials is developed. The transformation proceeds smoothly at room temperature without the exclusion of moisture or air. This phosphorylation reaction tolerates a wide range of functional groups and affords the phosphorylation products in moderate to good yields, thus providing a valuable method for the formation of aromatic carbon-phosphorus bonds.
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