期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 19, 页码 9131-9137出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b01704
关键词
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资金
- University of Nebraska Lincoln
- Donors of the American Chemical Society Petroleum Research Fund [53678-DNI10]
- National Science Foundation CAREER Award [DMR-1554918]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1554918] Funding Source: National Science Foundation
A metal-free protocol to generate phthalimide-N-oxyl (PINO) radicals from N-hydroxyphthalimide (NHPI) via a photoinduced proton-coupled electron transfer process is reported. Using donor-substituted aromatic ketones, such as 4,4'-bis(diphenylamino)benzophenone (DPA-BP), PINO radicals are efficiently produced and subsequently utilized to functionalize olefins to afford a new class of alkyl hydroperoxides. The DPA-BP/NHPI/O-2 photocatalytic system exhibits high efficiency toward the aerobic oxidation of beta-O-4 lignin models.
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