期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 3, 页码 1237-1243出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b02524
关键词
-
资金
- National Natural Science Foundation of China [21172151, 21321061, 21432006]
An efficient diastereo- and enantioselective [3 + 2] cycloaddition of heterosubstituted alkenes with oxiranes via selective C-C bond cleavage of epoxides has been developed. The reaction was catalyzed by a chiral N,N'-dioxide/Ni(II) catalyst, and a variety of chiral highly substituted tetrahydrofurans were obtained in up to 99% yield, 92/8 dr, and 99% ee.
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