期刊
CATALYSIS TODAY
卷 250, 期 -, 页码 123-133出版社
ELSEVIER
DOI: 10.1016/j.cattod.2014.05.011
关键词
Molybdenum carbides; alpha-MoC(1-x); beta-Mo2C; Toluene hydrogenation; TPR
资金
- Alberta Innovates-Energy and Environment Solutions (AIEES) through the Natural Sciences and Engineering Research Council of Canada (NSERC)
- Alberta Innovates-Energy and Environment Solutions (AIEES) through Nexen Industrial Research Chair in Catalysis for Bitumen Upgrading
- Canadian Foundation for Innovation
- Alberta Science and Research Authority
A convenient and practical method for the preparation of precursors to form molybdenum carbide materials using solutions of ammonium heptamolybdate and sucrose is presented. Depending on the temperature-programmed reaction protocol employed [i.e., low temperature and long times (523 K for 24h, 598K for 24h and 673K for 72h) or high temperature and short times (1073K for 30 min)], the C/Mo ratio of the precursors (i.e., 6.3, 3.6, 2.0, 1.0 and 0.6) and the presence or not of H-2, it is possible to produce nanocrystalline molybdenum carbide materials with the cubic or hexagonal phases. The two prepared phases of molybdenum carbide showed activity for the hydrogenation of toluene at 423 K to selectively produce methyl-cyclohexane. In the tested conditions, the hexagonal molybdenum carbide phase showed an initial higher activity but the deactivation of the catalyst was more pronounced than in the cubic molybdenum carbide catalyst. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据