Article
Chemistry, Multidisciplinary
Linping Yu, Long Chen, Qizhi Chen, Luli Feng, Ziyi Xu, Bo Nan, Xiyue Kang, Yuehui He
Summary: This study successfully fabricated a Ni-Cu alloy foil with a thickness of 12.0 micrometers using electrodeposition combined with vacuum sintering. The alloy foil showed excellent corrosion resistance and defect-free surface, providing new possibilities for the future development of integrated electronic or medical devices.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2021)
Article
Energy & Fuels
Yucen Kuang, Lechi Zhang, Longqi Wu, Xiaoqian Liu, Zhifang Wei, Jingbo Chen, Shengfu Zhang
Summary: Revealing the specific separation behavior of macerals is of great significance for the classification and utilization of coal resources. This article investigates the separation mechanism of macerals during coal upgrading through experimental and computational methods. The analysis of morphological, mineral, and structural differences of macerals reveals that the float-sink procedure with water bath heating achieves high purity for vitrinite and inertinite. The coal particle size and distribution of functional groups on inertinite surface affect the separation behavior.
Article
Materials Science, Multidisciplinary
Di Wu, Libin Liu, Lijun Zeng, Wenguang Zhu, Wanlin Wang, Xiaoyong Zhang, Junfeng Hou, Baoliang Liu, Jiafeng Lei, Kechao Zhou
Summary: This study utilized the pseudo-spinodal mechanism to design a high-strength titanium alloy, confirming through diffusion multiple experiments and CALPHAD results the composition range and method to obtain the ultrafine alpha phase. The designed alloy showed excellent mechanical properties but limited ductility due to a large number of alpha/beta interfaces.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Engineering, Aerospace
Yangguang Zhang, Yueliang Chen, Yong Zhang, Guixue Bian, Chenguang Wang, Andong Wang
Summary: The initial corrosion behavior and mechanism of 7B04 aluminum alloy under acid immersion and salt spray environments were studied using various characterization methods. Pitting corrosion occurred in the initial corrosion stage, and the potential difference between second phase particles was identified as the main cause. The main components of the corrosion products were Al2O3, Al(OH)(3), and AlCl3, with a higher generation rate under the salt spray environment. The Volta potential gradually shifted in a positive direction, indicating an inhibitory effect of corrosion products on corrosion. The corrosion current density was significantly lower for the salt spray sample, suggesting that a thicker corrosion product layer provided stronger inhibition of corrosion reaction.
CHINESE JOURNAL OF AERONAUTICS
(2022)
Article
Energy & Fuels
Yuxiang Peng, Pravin S. Shinde, Ramana G. Reddy
Summary: The effect of Ni-coating on the corrosion behavior of Incoloy 800H alloy in molten salt was investigated. It was found that Ni-coating improved the corrosion resistance and decreased the corrosion rate of 800H alloy. A diffusion model for Ni-coated 800H alloy was presented to describe the diffusion behavior of Cr, Fe, and Ni elements.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2022)
Article
Chemistry, Physical
Shuai Gao, Yafei Huang, Ye Xiong, Xugeng Guo, Jinglai Zhang, Li Wang
Summary: In this study, three quaternary ammonium based dicationic ILs were synthesized and applied as corrosion inhibitors for magnesium alloy. Among them, [DMBAB][Trp]2 showed the best corrosion protection efficiency for AZ91D Mg alloy in 0.5 wt% NaCl solution.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Multidisciplinary
Y. Ren, S. Yang, X. Ma, Z. Qi, C. Zhang, X. Liu, X. Tan, S. Sun
Summary: The study demonstrated that modifying double-vacancy defect graphene can enhance the stability of the heterostructure and achieve the highest adhesion work. Modifying defective graphene can increase the adsorption energy of lithium atoms on the surface and interface, thereby inhibiting dendritic growth.
MATERIALS TODAY CHEMISTRY
(2021)
Article
Materials Science, Multidisciplinary
Lizhi Qin, Wei Wu, Xuequn Cheng, Feifan Xu, Chao Liu, Xiaogang Li
Summary: This study investigated the initial corrosion behavior of Fe-Mn-Al-C-Ni lightweight steels with different B2-phase grain sizes in 3.5 wt.% NaCl solution. Quasi-in-situ short-period immersion tests and electrochemical experiments revealed the immersion corrosion process of Fe-Mn-Al-C-Ni mild steel and the selective corrosion characteristics of the alloy surface. Results showed that the grain size of granular B2 phase was significantly reduced compared to the striped B2 phase, and the diffuse distribution of granular B2 phase in the matrix led to a more uniform corrosion behavior and improved corrosion resistance of the alloy.
Article
Green & Sustainable Science & Technology
Song Cheng, Baolin Xing, Changliang Shi, Yanhe Nie, Hongying Xia
Summary: A low-cost and selective adsorbent CC-CCW@DM was prepared by modifying crofton weed with 1,3-diaminoguanidine monohydrochloride for efficient removal of Pb(II). The adsorbent showed good selectivity and high adsorption capacity for Pb(II) removal, with recycling experiments demonstrating its cost-saving potential.
JOURNAL OF CLEANER PRODUCTION
(2021)
Article
Chemistry, Multidisciplinary
Lingyan Zhang, Kai Xu, Tulu Liang, Jin Shi
Summary: In this paper, surface modification of materials using mechanical alloying and electron beam irradiation is investigated. The results show that the Sn-rich Ni-Sn alloy layer obtained through this method has a higher surface hardness compared to the initial pure nickel layer. The atomic structure of the Sn-doped nickel substrate in the alloy layer is also simulated to understand the improvement mechanism.
Article
Electrochemistry
Huan-Wen Chen, Han Lin, Chao-Yu Huang, Chian-Huei Shi, Chao-Sung Lin
Summary: The initial corrosion of AZ31B Mg alloy in chloride and sulfate solutions was studied in detail. The results showed that the initial corrosion of AZ31B in sulfate solution was more severe compared to chloride solution. Local corrosion was observed in chloride solution, but not in sulfate solution.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2022)
Article
Materials Science, Multidisciplinary
Ramesh S. Bhat, K. B. Munjunatha, Subrahmanya Bhat, K. Venkatakrishna, A. Chitharanjan Hegde
Summary: In this study, Zn-Ni-Fe alloy coatings were electrodeposited on low carbon steel and the effects of various factors on the coating properties were investigated. The results showed that the new alloy coating exhibited better corrosion resistance properties and could be applied in industrial applications such as machine tools, bolts, and nuts in the automobile.
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
(2022)
Article
Materials Science, Multidisciplinary
Pan Yi, Chaofang Dong, Kui Xiao, Xiaogang Li
Summary: The study revealed that the corrosion behavior of SAC305 alloy is influenced by factors such as galvanic corrosion, electronic structure, and material microstructure. The calculation of electronic density of state helps explain the corrosion behavior, and a corresponding corrosion failure mechanism has been proposed.
Article
Chemistry, Physical
Zhijun Zhang, Ziting Yuan, Li Zhuang, Jun Chai
Summary: In this study, the microscopic adsorption mechanism of PAM on kaolinite surface in the presence of Ca2+ was investigated using DFT. The adsorption of PAM on kaolinite (001) surface was found to be dominated by three strong hydrogen bonds, while non-bonding interactions were observed on the kaolinite (00-1) surface. The presence of Ca2+ promoted the adsorption of PAM on the kaolinite (001) surface, but inhibited adsorption on the kaolinite (00-1) surface.
CHEMICAL PHYSICS LETTERS
(2021)
Article
Chemistry, Physical
Chen-Hao Yeh, Abdul Hannan Khan, Tsuyoshi Miyazaki, Jyh-Chiang Jiang
Summary: This study reveals through theoretical analysis that the iSBU site in the Ni-MOF-74 material exhibits the strongest adsorption energy for methane molecules, with the C-H horizontal ellipsis and weak Agostic interactions being critical factors affecting the adsorption energy. Additionally, DOS and EDD analyses demonstrate that interactions play a crucial role in the adsorption of methane molecules on Ni-MOF-74.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Article
Chemistry, Physical
Fan Liu, Lei Li, Shuhong Xu, Jiabin Guo, Ying Ling, Yongyi Zhang, Wenbin Gong, Lei Wei, Chunlei Wang, Qichong Zhang, Qingwen Li
Summary: An effective strategy of cobalt-doped MoS2 nanosheets directly grown on carbon nanotube fibers was proposed to develop efficient cathodes for fiber-shaped aqueous zinc-ion batteries (FAZIBs). The introduction of cobalt-ion activates the transformation of MoS2 crystal structure and expands the interlayer spacing, resulting in remarkable capacity, high rate capability, and impressive durability.
ENERGY STORAGE MATERIALS
(2023)
Article
Mathematics, Applied
Wenbin Gong, Yaqiang Wang
Summary: This paper presents new criteria for judging the positive definiteness of even-order real symmetric tensors, which expand the range of judgment by scaling the elements of the tensor with an increasing constant k. In addition, sufficient conditions for judging the positive definiteness of even-order real symmetric tensors are proposed. Numerical examples are provided to illustrate these new results.
Article
Nanoscience & Nanotechnology
Chunyan Zhao, Lingsheng Zhang, Shuang Jing, Shuo Kong, Xiaojie Zhang, Xiong Lan, Yongbao Feng, Chenglong Liu, Konghu Tian, Wenbin Gong, Qiulong Li
Summary: In this study, a self-standing electrode with heterostructure was successfully constructed to solve the issues of low conductivity, poor electrochemical kinetics, and unsatisfactory cycling performance of cobalt oxide in lithium-ion batteries. The experimental results showed that the construction of heterostructure greatly improved the conductivity and lithium ion adsorption energy of the material, leading to remarkable capacity, excellent performance at high current density, and remarkable cyclic stability of the battery.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Jinlin Yang, Wenbin Gong, Fengxia Geng
Summary: Defective cobalt manganese oxide nanosheets are reported as cathode material for aqueous Al-ion batteries, showing high energy density and cycling stability. The study offers a new pathway to building next-generation high-energy aqueous rechargeable metal batteries.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Engineering, Environmental
Lei Li, Yongjiang Wang, Wenbin Gong, Meijin Lin, Lei Wei, Qingwen Li, Qichong Zhang, Litao Sun
Summary: Organic carbonyl compounds as electrode materials have promising potential for next-generation aqueous rechargeable batteries. However, their poor cycling performance, caused by high solubility of discharge products, has limited their broader application. In this study, we developed a strategy to enhance the cyclability of aqueous zinc-organic batteries by modifying the structure of perylene-3,4,9,10-tetracarboxylic dianhydride. The modified cathode showed excellent discharge capacity and long cycling stability, with a reversible co-insertion mechanism of Zn2+/H+ at the carbonyl site.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Jiajia Xia, Yurong Zhou, Jian Zhang, Tianyu Lu, Wenbin Gong, Dengsong Zhang, Xiaona Wang, Jiangtao Di
Summary: This study proposes magnesium-doped layered manganese dioxide (Mg-MnO2) as cathode materials for aqueous zinc-ion batteries (ZIBs) to improve their performance. Mg-MnO2 with a larger specific surface area provides more electroactive sites and enhances the capacity of ZIBs. The electrical conductivity and ion diffusion coefficients of Mg-MnO2 are also improved by doping cations and oxygen vacancies in the MnO2 lattices. The assembled Zn//Mg-MnO2 battery exhibits a high specific capacity and reversible redox reaction between Zn2+ and MnOOH, promoting capacity and stability.
Article
Chemistry, Physical
Long Chen, Meng He, Wenbin Gong, Peiying Hu, Shuanglong Yuan, Aiping Chen, Lei Wei, Qichong Zhang, Qingwen Li
Summary: All-inorganic metal halide perovskites (MHPs) have great potential for flexible electronics due to their excellent photo-physical properties and low-cost fabrication. However, their suboptimal quantum yield and stability have hindered their diverse wearable applications. A water evaporation crystallization strategy is proposed to prepare salt-shelled metal halide solids, which exhibit narrow photoluminescence and high quantum yield. These materials can be used in waterborne transparency inks and flexible photoluminescent films, as well as in high-performance positive friction materials for triboelectric nanogenerators. Furthermore, a wearable photoluminescent sensor with voltage response range and quick response time is constructed. These metal halides open up possibilities for lightweight and multifunctional wearable electronics.
Article
Nanoscience & Nanotechnology
Hairong Mai, Qianchen Wang, Longhua Sun, Xiaodong Meng, Shang Chen, Ji Zhou, Yuncan Jia, Manyun Wang, Xinyi Han, Xueqin Zhou, Wenbin Gong, Guangxu Zhu, Jingyu Li, Christopher W. Bielawski, Jianxin Geng
Summary: Nonstoichiometric compounds are widely used in contemporary energy technologies. A new method for synthesizing N-doped porous graphitic carbon hybridized with nonstoichiometric scandium oxide is reported, and the composite is shown to significantly enhance sulfur cathode kinetics in lithium-sulfur batteries.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Fan Liu, Shuhong Xu, Wenbin Gong, Kaitian Zhao, Zhimin Wang, Jie Luo, Chunsheng Li, Yan Sun, Pan Xue, Chunlei Wang, Lei Wei, Qingwen Li, Qichong Zhang
Summary: By introducing fluorescent carbon dots with abundant zincophilic functional groups as bifunctional electrolyte additives, fluorescent fiber-shaped aqueous zinc-ion batteries (FFAZIBs) have been developed, achieving high energy density and long-term cyclability. The one-dimensional structure of FFAZIBs ensures the same luminance in all directions, enabling the form of multicolor display-in-battery textiles.
Article
Engineering, Environmental
Xianzhen Wang, Gang Ding, Zhenping Ma, Ziming Xu, Yongbao Feng, Wenbin Gong, Chenglong Liu, Konghu Tian, Zhenzhong Yong, Qiulong Li
Summary: A new zinc anode with a 3D porous host compounded with TiO2 nanowire arrays (NWAs) decorated with rGO and CNTs (TGC) was constructed to solve the problems of dendrite growth, surface passivation, and corrosion of the zinc anode. The new zinc anode enables uniform deposition of zinc, resulting in stable performance and long lifespan.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Thermodynamics
Wenbin Gong, Gaowen Liu, Kai Chen, Aqiang Lin, Qing Feng, Zhiwu Wang
Summary: The interaction between turbine rim seal flow and the mainstream has become a major limitation on the performance and precision design of large-power turbine systems as the turbine inlet temperature increases. This study aims to develop a novel modeling experiment method to effectively analyze the interaction mechanism and sealing effectiveness of turbine rim seal flow under high temperature difference conditions. By proposing a new set of nondimensional parameters and compared with conventional parameters, the proposed method improves the accuracy of sealing performance prediction by approximately 26.1%.
INTERNATIONAL JOURNAL OF THERMAL SCIENCES
(2023)
Article
Chemistry, Physical
Yong Liu, Siqi Zhu, Zhen Zhang, Qiong Sun, Cao Wu, Wenbin Gong, Lixing Kang, Yong Yang
Summary: Rechargeable zinc-ion batteries (ZIBs) utilizing zinc-manganese oxide as the cathode showed impressive capacity and cycling stability. The use of an ultra-thin monocrystalline structure enhanced the electro-chemical reaction, improved surface interface interactions, and facilitated ion diffusion kinetics. This study provides a novel methodology for the development of high-performance and mass-produced ZIBs systems.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Physics, Applied
Ji Zhou, Wenbing Gong, Xiaodong Meng, Jiawen Zhang, Xueqin Zhou, Shang Chen, Christopher W. Bielawski, Jianxin Geng
Summary: Replacing a linear ether with a macrocyclic amine in the electrolyte of lithium-sulfur batteries can overcome challenges such as slow cathode kinetics, the shuttle effect, and dendrite growth on the anode. The new electrolyte forms a stable solvation structure that reduces overpotentials for Li2S nucleation and decomposition and suppresses Li dendrite growth and the shuttle effect of polysulfides. Batteries prepared with this electrolyte exhibit outstanding performance.
APPLIED PHYSICS REVIEWS
(2023)
Article
Energy & Fuels
Chunyan Zhao, Jinwen Fu, Ao Shen, Lingsheng Zhang, Shuo Kong, Yongbao Feng, Wenbin Gong, Konghu Tian, Qiulong Li
Summary: A novel architecture of spherical nanoflower MoS2/MoO3 heterostructures is designed for lithium-ion batteries, which shows high capacity and rate capability, as well as outstanding cycling performance.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Chemistry, Multidisciplinary
Kaiping Zhu, Can Guo, Wenbin Gong, Qinghua Xiao, Yagang Yao, Kenneth Davey, Qinghong Wang, Jianfeng Mao, Pan Xue, Zaiping Guo
Summary: In this study, an electrostatic field layer (EFL) was established using an electrolyte additive of cobalt tetraaminophthalocyanine (Co(TAPC)) to address the instability issue of the Zn metal/electrolyte interface, parasitic reactions, and dendritic growth, resulting in low Coulombic efficiency (CE) and poor cycle life. The Co(TAPC) with a planar and large conjugated ring structure could preferentially absorb on the Zn metal anode to form a zincophilic EFL, which prevents direct contact of Zn and water, suppresses side reactions, promotes desolvation and Zn2+ diffusion kinetics, and balances the space electric field, thereby enabling high-rate and dendrite-free Zn deposition.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Liuming Wei, Jingwen Li, Yonggang Li, Qirong Zheng, Fan Cheng, Chuanguo Zhang, Jingyu Li, Gaofeng Zhao, Zhi Zeng
Summary: This study investigates the influence of He-V complexes on H behaviors on different W surfaces using DFT calculations. The results show that H dissolution is most difficult but H trapping is easiest on the W (110) surface, while the opposite is true on the W (111) surface. Moreover, the presence of He-V complexes increases the difficulty of H diffusion from bulk to surface and desorption.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Yan Meng, Song Zeng, Chen Chen, Chaowen Zhu, Huahai Shen, Xiaosong Zhou, Xiaochun Han
Summary: The characteristics of magnetron sputtered Cr coatings vary with different temperature, bias voltage, and pressure. Coatings with random orientation, good crystallinity, and small grain size exhibit favorable oxidation behavior, while coatings with strong (200) texture, poor crystallinity, and large grains have many intrinsic defects that are detrimental to the protection property of the Cr coatings.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Xinyuan Xu, Zefeng Yu, Wei-Ying Chen, Aiping Chen, Arthur Motta, Xing Wang
Summary: This study presents an automated approach for characterizing grain morphology in TEM images recorded during ion irradiation. By combining a machine learning model and a computer vision algorithm, comparable results to human analysis can be achieved with significantly reduced analysis time. Researchers can train their own models following the procedures described in this study to automate grain morphology analysis of their own TEM images.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Shihao Wu, Dong Wang, Yapei Zhang, Koji Okamoto, Marco Pellegrini, Wenxi Tian, Suizheng Qiu, G. H. Su
Summary: The oxidation and degradation mechanisms of Cr coating on Zr alloy cladding under high temperature steam atmosphere are summarized, and a mathematical analysis model is established to predict the changes in coating thickness. The model is applied in the analysis of structure evolution under different conditions.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
V. Diaz-Mena, J. de Prado, M. Roldan, I. Izaguirre, M. Sanchez, M. Rieth, A. Urena
Summary: The brazeability of a cupronickel alloy was evaluated as a filler alloy for high-temperature joining of tungsten to steel. The study investigated the brazing conditions and the impact of the selected filler on the joint quality using numerical software. The results showed different metallurgical interactions and diffusion phenomena between the filler alloy and the base materials at different temperatures. The study emphasized the importance of selecting a suitable filler to mitigate residual stresses in the joints.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Pengcheng Zhu, Yajie Zhao, Yan-Ru Lin, Jean Henry, Steven J. Zinkle
Summary: This study investigates the effect of heavy-ion irradiation on radiation hardening in high-purity binary alloy Fe18Cr. Nanoindentation testing and high-quality TEM imaging were conducted to extract hardness and microstructure information. The strength factor was accurately calculated based on the detailed TEM characterization of irradiated microstructures, and a refined hardening superposition method was applied to quantify the mechanical properties of ion-irradiated materials.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Bin Wu, Haixia Ning, Hanzhen Zhu, Jianjun Chen, Kang Wang, Daiyu Zhang, Fu Wang, Qilong Liao
Summary: This study discusses the effects of ZrO2 and B2O3 on the phase composition and properties of SAP-based glass-ceramics. The results show that ZrO2 addition improves the formation of NZP phase while restricting the crystallization of AlPO4 phases. The correct ratios of ZrO2 and B2O3 allow only the formation of NZP phase within the SAP glass.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Hwasung Yeom, Greg Johnson, Benjamin Maier, Tyler Dabney, Kumar Sridharan
Summary: Cr-Nb bilayer coatings were developed using cold spray deposition to improve the limiting operational temperature of Cr-coated Zr-alloy system. The coatings exhibited outstanding oxidation resistance at high temperatures and formed continuous intermetallic compound layers at the interfaces.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Padhraic L. Mulligan, Andrew T. Nelson, Chad M. Parish, Patrick A. Champlin, Xiang Chen, Daniel Morrall, Jason M. Harp
Summary: Environmental barrier coatings are being developed to reduce oxidation and embrittlement in Zr-based materials. Chromium nitride is a candidate for this application, but understanding its impact on irradiation-induced creep and microstructure is critical.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Dexuan Yan, Xinlei Cao, Ke Shen
Summary: This study investigated the purification mechanism of polycrystalline graphite by comparing IG-11 graphite with IG-110 nuclear grade graphite. The analysis revealed that metallic impurities in IG-11 were primarily segregated within graphite porosities, while IG-110 demonstrated a significant reduction in impurities. This research contributes to the development of innovative graphite purification techniques for greater purity and stronger oxidation resistance.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Wei Xu, Wei Peng, Lei Shi, Qi Sun
Summary: This paper investigates the oxidation and shape evolution of matrix graphite in high temperature gas-cooled reactors during air-ingress accidents. A reaction kinetics model is established and computational fluid dynamics with a dynamic mesh method is used to simulate the oxidation process. The results show that the geometric shape of graphite changes significantly with increasing flow rate, and the graphite pebbles tend to form a structure with a narrow front and wide tail.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Allison Harward, Casey Elliott, Michael Shaltry, Krista Carlson, Tae-Sic Yoo, Guy Fredrickson, Michael Patterson, Michael F. Simpson
Summary: This paper investigates the hygroscopic properties of eutectic LiCl-KCl absorbed into zeolite-4A. The study finds that water absorption and corrosion worsen with increasing salt loading. It also suggests that the salt can be stored in a non-inert atmosphere for a certain period of time.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Takaaki Koyanagi, Xunxiang Hu, Christian M. Petrie, Gyanender Singh, Caen Ang, Christian P. Deck, Weon-Ju Kim, Daejong Kim, James Braun, Yutai Katoh
Summary: This study provides critical experimental data on the effects of irradiation on the hermeticity of SiC composite cladding, finding that irradiation can cause a decrease in hermeticity and cracking, and coating the outer surface can mitigate the cracking issue.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
S. Krat, A. Prishvitsyn, Yu. Gasparyan
Summary: This study proposes a probabilistic and diffusion-based model to describe the co-deposition of multiple hydrogen isotopes with slowly grown metal layers. The model calculates the relative concentrations of different hydrogen isotopes in the co-deposited metal layers. It is found that if hydrogen isotopes have different detrapping energies, only the isotope with the highest detrapping energy shows a monotonic decrease in concentration with deposition temperature. Furthermore, the study evaluates the uncertainty of tritium concentration in the co-deposited layer based on the uncertainty in detrapping energy of tritium and deuterium, predicting a >10% tritium concentration uncertainty for a 0.01 eV difference.
JOURNAL OF NUCLEAR MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Tijo Vazhappilly, Arup Kumar Pathak
Summary: This study investigates the effect of Ce atom substitution in UO2 on its thermophysical properties using density functional theory. The results show that the Ce substitution levels and the oxidation state of Ce/U atoms strongly influence the band structure and specific heat capacity of the UO2 lattice. These findings provide important insights into the fuel properties of UO2 under reactor conditions.
JOURNAL OF NUCLEAR MATERIALS
(2024)