期刊
CATALYSIS TODAY
卷 252, 期 -, 页码 93-99出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cattod.2014.09.023
关键词
Tebuconazole; Photocatalysis; Response surface methodology; Transformation products; Scavengers
资金
- European Union (European Social Fund - ESF)
- Greek national funds through the Operational Program Education and Lifelong Learning of the National Strategic Reference Framework (NSRF) - Research Funding Program: Archimedes III. Investing in knowledge society through the European Social Fund
- research project Archimedes III: Synthesis and characterization of novel nanostructured materials and study of their use as water purification systems [MIS 383566]
The photocatalytic degradation of tebuconazole (TEB), a common fungicide with numerous agricultural and urban uses, has been investigated under simulated solar irradiation. Response surface methodology (RSM) was employed to assess individual and interactive effects of the three main independent parameters (initial TEB concentration, irradiation intensity and catalyst concentration) on the efficiency of the process. Optimization results showed that maximum TEB degradation and TOC removal was achieved at the optimum conditions: C-TEB = 1 mg L-1, C-TiO2 - 550 mg L-1, I=650 W m(-2). By means of high resolution accurate mass liquid chromatography (HR-LC-MS) and gas chromatography-mass spectroscopy (GC-MS) nine transformation products were identified. The transformation of TEB pathways was found to proceed through tert-butyl chain cleavage, hydroxylation, oxidation and dechlorination pathways. Scavenging experiments showed that the degradation mechanism of TEB was mainly driven by HO center dot and h(+). Finally, the application of an acute toxicity test (Vibrio fischeri) to selected water samples resulted in a non-inhibitory effect of the bacterial bioluminescence. (C) 2014 Elsevier B.V. All rights reserved.
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