期刊
CHINESE JOURNAL OF POLYMER SCIENCE
卷 41, 期 6, 页码 859-865出版社
SPRINGER
DOI: 10.1007/s10118-022-2872-4
关键词
Recyclable thermosets; Borate ester; Polyurea-urethane; Stimuli-cleavage
Covalent crosslinking in thermosets often results in excellent mechanical properties and solvent resistance, but limited degradability and recyclability. In this study, a polyurea-urethane thermoset with borate ester crosslinking points is reported, which can undergo controllable de-crosslinking in response to acetate acid. The thermoset exhibits remarkable mechanical properties and outstanding solvent resistance due to high crosslinking density and intermolecular hydrogen bonding. Furthermore, the de-crosslinked product can be reprocessed to generate a new thermoplastic material.
Covalent crosslinking points within thermosets generally result in excellent mechanical properties and solvent resistance yet lead to limited degradability and recyclability. Those thermosets become degradable or recyclable if crosslinking points are cleavable or reversible. Following this principle, we report a kind of polyurea-urethane thermoset with borate ester as its crosslinking point to enable a controllable de-crosslinking in response to acetate acid. Such a thermoset presents remarkable mechanical properties as well as outstanding solvent resistance capability, due to the high crosslinking density and intermolecular hydrogen bonding. Furthermore, the de-crosslinked product can be reporcessed to generate a brand new thermoplastic material.
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