Indole HDN Using Iridium Nanoparticles Supported on Titanium Nanotubes

The HDN of indole was studied over iridium modified titanate nanotube catalyst. Titanium nanotube was prepared by the alkaline hydrothermal method. Iridium was added by wetness impregnation. The activity was compared with Ir-TiO2 and commercial NiMo/Al2O3 catalysts. The catalysts prepared were characterized by X-ray diffraction (XRD), N-2 adsorption isotherms, UV-Vis-DRS, FTIR, XPS, TEM, Py-FTIR and H-2-Chemisorption. XRD, N-2 isotherms and UV-vis-DRS confirmed the nanotube structure. The analysis showed that the mesoporous structure was maintained after Ir incorporation. The results showed that titanate nanotube as support significantly reduce the size of iridium crystallites and improves its dispersion considerably. Iridium titanate nanotube presented abundant and strong Bronsted acidity compared with TiO2 iridium catalyst. According a kinetic study, Ir-TNT was the most active catalyst for indole HDN, in mild conditions in a Batch reactor. The Bronsted acidity in synergic effect with Lewis acidity and hydrogenolysis capacity of iridium species were the responsible for the good activity. [GRAPHICS] .

Automated summary

This study investigated the HDN of indole using iridium modified titanate nanotube catalyst. The results showed that the iridium titanate nanotube catalyst exhibited excellent activity and dispersion, as well as abundant and strong Bronsted acidity. This catalyst shows great potential for the conversion of indole.