4.6 Article

The interaction mechanism of photogenerated carriers and piezoelectric charges of a photoactive piezoelectric nanogenerator

期刊

APPLIED PHYSICS LETTERS
卷 121, 期 26, 页码 -

出版社

AIP Publishing
DOI: 10.1063/5.0131015

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资金

  1. National Natural Science Foundation of China
  2. Natural Science Foundation of Henan Province in China
  3. [51872074]
  4. [12204153]
  5. [212300410004]
  6. [212300410124]

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Despite their potential as a self-powered photodetector and pressure sensor, the interaction mechanism between photogenerated carriers and piezoelectric charges in photoactive piezoelectric nanogenerators (PENGs) remains insufficiently investigated. This study fabricates photoactive PENGs based on a methylammonium lead halides-poly(vinylidene) (MAPI-PVDF) composite, and explores the interaction mechanism between photogenerated carriers and piezoelectric charges using various techniques. The results demonstrate a screening effect of the photogenerated carriers on the piezoelectric potential, and a promotion of carrier recombination by the piezoelectric charges. This work opens up new possibilities for designing PENGs with multiple application modes and contributes to the development of piezoelectric materials.
Despite the fact that photoactive piezoelectric nanogenerators (PENGs) have been getting more attention due to their significant potential as a self-powered photodetector and pressure sensor, investigations on the interaction mechanism between photogenerated carriers and piezoelectric charges are still insufficient. In this study, photoactive PENGs based on methylammonium lead halides-poly(vinylidene) (MAPI-PVDF) composite were fabricated, in which the presence of MAPI in the PVDF matrix plays a dual role in enhancing the nucleation of the electroactive beta-phase as well as inducing photoactivity in the composite. It has an optimal open-circuit voltage of 4.7 V and short-circuit current of 0.2 mu A at 10 wt. % concentration of MAPI under illumination, which is nearly halved in the dark. Furthermore, we have thoroughly explored the interaction mechanism between photogenerated carriers and piezoelectric charges by piezoresponse scanning force microscopy techniques, photoluminescence spectroscopy, and a bandgap analysis. The results demonstrate that the photogenerated carriers screen part of the piezoelectric potential induced by the piezoelectric charges, while the piezoelectric charges promote more photogenerated carriers recombination. This work opens up horizons for the piezoelectric community in designing photoactive PENGs with multiple application modes and provides an effective approach to the development of piezoelectric materials. Published under an exclusive license by AIP Publishing.

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