期刊
CATALYSIS COMMUNICATIONS
卷 71, 期 -, 页码 42-45出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2015.08.015
关键词
Ethane dehydrogenation; Ga2O3; HSSZ-13; Selectivity; Pore geometry
资金
- National Natural Science Foundation of China [20633030, 20773027, 20773028, 21273043]
- Science & Technology Commission of Shanghai Municipality [08DZ2270500]
Dehydrogenation of ethane to ethylene in the presence of CO2 was investigated over gallium oxide supported on HSSZ-13 with different Si/Al ratios. These catalysts exhibited higher activity as well as higher selectivity in comparison to HZSM-5 supported ones. 34% ethane conversion with 86.9% selectivity to ethylene could be obtained. The enhanced catalytic performance of Ga2O3/HSSZ-13 can be attributed to unique pore geometry of SSZ-13 support. However, the stability is not as good as that of Ga2O3/HZSM-5, owing to easy coking in channel with smaller pore-opening size. (C) 2015 Elsevier B.V. All rights reserved.
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