期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 425, 期 -, 页码 340-348出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2016.10.020
关键词
Visible light photocatalysis; Phosphorus-doped g-C3N4; TiO2; Photodegradation
资金
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
Photocatalysts Phosphorus-Doped g-C3N4 (P(x%)-g-C3N4) were successfully prepared by a two-step method using melamine and phosphonitrilic chloride trimer (Cl6N3P3). Then, the Phosphorus-doped g-C3N4 sheets coated with TiO2 nanoparticles (P(x%)-g-C3N4/TiO2) were prepared by solvent-thermal method. The as-prepared P(x%)-g-C3N4/TiO2 composites showed enhanced light absorption and photocatalytic properties in visible light region. The morphology of g-C3N4 nanosheets and square flake TiO2 nanoparticles were analyzed with field emission scanning electron microscopy (FESEM) and scanning electron microscopy (SEM). X-ray photoelectron spectroscopy (XPS) proved that the P-C bonds were generated in P(x%)-g-C3N4. Photoluminescence (PL) spectra revealed that the phosphorus doping improved the separation and transfer of photogenerated electrons and holes in P(x%)-g-C3N4, UV-vis diffuse reflectance spectra (UV-vis DRS) indicated that the P(x%)-g-C3N4/TiO2 heterostructure enhanced the absorption of visible light. The photocatalytic activity of the P(x%)-g-C3N4 was evaluated by photo catalytic degradation of Methyl Blue (MB) under visible light irradiation. The result indicated that the P(0.1%)-g-C3N4/TiO2 composite present considerably high photocatalytic degradation activities on MB, and the degradation of MB by P(0.1%)-g-C3N4/TiO2 were 5.1 times and 2.9 times as high as that of g-C3N4 and P25, respectively. At the end of article, a possible photocatalytic mechanism was discussed based on the experimental results. (C) 2016 Elsevier B.V. All rights reserved.
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