期刊
JOURNAL OF MEMBRANE SCIENCE
卷 504, 期 -, 页码 40-46出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.memsci.2015.12.050
关键词
Forward osmosis (FO); Membrane fouling; Osmotic microbial fuel cell (OsMFC); Internal resistance; Ion flux
资金
- National Natural Science Foundation of China [51522812]
- National 863 Project [2011AA060901]
- Natural Science Foundation of Jiangsu Province, China [BK20131184]
- Collaborative Innovation Center of Suzhou Nano Science and Technology
Osmotic microbial fuel cells (OsMFC), which incorporates forward osmosis (FO) in MFC design, favors an improved electricity generation and effluent quality over conventional MFCs that use proton exchange membranes. However, fouling of the FO membrane during long-term operation is unavoidable, and it is unclear how this would affect the MFC performance. Here, we found that the current generation of an OsMFC increased upon membrane fouling despite of the loss of water flux, and the internal resistance decreased relative to the pristine membrane conditions. A further examination of the pH changes and ion flux by electrochemical test revealed that the diffusion of protons and other ions through the membrane was significantly promoted upon fouling. The underlying mechanisms of the fouling-induced diffusion enhancement were also investigated. The finding of this work broadens our understanding about the fouling properties of FO membrane, and implies that FO membrane could serve as a potential fouling tolerant separator for MFCs and other bioelectrochemical applications. (C) 2016 Elsevier B.V. All rights reserved.
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