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Activation Mechanism of Coal Gangue and Its Impact on the Properties of Geopolymers: A Review

期刊

POLYMERS
卷 14, 期 18, 页码 -

出版社

MDPI
DOI: 10.3390/polym14183861

关键词

geopolymer; coal gangue; activation mechanism; toxic curing; solid waste utilization; geopolymer property

资金

  1. National Natural Science Foundation of China [52179132]
  2. Program for Science and Technology Innovation Talents in universities of Henan province [20HASTIT013]
  3. Sichuan University, State Key Lab Hydraul and Mt River Engn [SKHL2007]
  4. Open Research Fund Program of State Key Laboratory of Eco-hydraulics in Northwest Arid Region, Xi'an University of Technology [2021KFKT-10]
  5. Scientific and technological research project in Henan province [212102310934, 212102210452]
  6. Master innovation Ability Enhancement Project of North China University ofWater Resources and Electric Power [YK-2021-16]

向作者/读者索取更多资源

This paper investigates the application of coal gangue in geopolymer preparation. By adjusting different factors, coal gangue geopolymers can have higher mobility and mechanical strength. Additionally, coal gangue can also be used for solidifying radioactive waste.
Coal gangue is one of the industrial solid wastes that may harm the human body through the ecosystem for a long time. Using coal gangue in geopolymer preparation can effectively reduce cement output and meet the sustainability requirements. In this paper, the physical and chemical characteristics, including the heavy metal content, of coal gangue from different producing areas are described. Then, the mechanism of physical activation (mechanical and thermal activation), chemical activation, and compound activation of coal gangue are illustrated. The machinability, as well as the mechanical, microscopic, and toxicity consolidation properties of geopolymers prepared from coal gangue, are summarized and analyzed. The results indicate that the coal gangue geopolymers can have higher mobility and mechanical strength than cement-based composites by adjusting high calcium element material, alkali activator content, Na2SiO3 modulus, and curing condition. After physical activation, coal gangue is used in geopolymer preparation with a chemical activator (alkali excitation agent), which effectively forms a three-dimensional silicon aluminate polymer network. The pore structure is dense, the physical fixation and chemical bonding are strengthened, and the solidification and adsorption of heavy metal ions are improved. Further, it can also be applied to solidifying radioactive waste, which is following the future development direction.

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