4.8 Article

Electrochemically exfoliated graphene oxide/iron oxide composite foams for lithium storage, produced by simultaneous graphene reduction and Fe(OH)3 condensation

期刊

CARBON
卷 84, 期 -, 页码 254-262

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2014.12.007

关键词

-

资金

  1. European Union Seventh Framework Programme [604391]
  2. EC Marie-Curie ITN-GENIUS [PITN-GA-2010-264694]
  3. Future and Emerging Technologies (FET) programme within the Seventh Framework Programme for Research of the European Commission, under FET-Open Grant [309056]
  4. Operative Program FESR of Regione Emilia-Romagna - Attivita [1.1.1]

向作者/读者索取更多资源

We describe the production of graphene-based composites for energy storage, obtained by a combination of electrochemical and solution processing techniques. Electrochemically exfoliated graphene oxide sheets (EGO) are produced using an original setup that allows fast expansion of graphite flakes and efficient exfoliation of expanded graphite via an electrochemical route. The sheets are deposited on a sacrificial nickel foam together with an iron hydroxide colloidal precursor. Calcination treatment simultaneously renders the EGO foam conductive and transforms Fe(OH)(3) into hematite (alpha-Fe2O3), yielding a nanoporous Fe2O3 layer on the surface of the mesoporous EGO foam, creating an ideal structure for lithium storage. The obtained graphene/metal oxide hybrid is a continuous, electrically conductive three-dimensional (3D) composite featuring a hierarchical meso-nano porous structure. A systematic study of these composites, varying the Fe2O3:EGO ratio, is then performed to maximize their performance as nanostructured electrodes in standard coin cell batteries. (C) 2014 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

Graphene-Paper-Based Electrodes on Plastic and Textile Supports as New Platforms for Amperometric Biosensing

Fabrizio Poletti, Alessandra Scida, Barbara Zanfrognini, Alessandro Kovtun, Vitaliy Parkula, Laura Favaretto, Manuela Melucci, Vincenzo Palermo, Emanuele Treossi, Chiara Zanardi

Summary: Exfoliating graphite into graphene sheets allows the researchers to produce graphene paper, which is conductive, flexible, and processable. Graphene paper is used for electronic applications, demonstrating superior performance in antennas, electronics, and sensing. The stable deposition of enzymes on the electrode surface shows the potential applicability of graphene paper in biosensing.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Polarization Control in Integrated Silicon Waveguides Using Semiconductor Nanowires

Ali Emre Kaplan, Valerio Vitali, Valeria Demontis, Francesco Rossella, Andrea Fontana, Samuele Cornia, Periklis Petropoulos, Vittorio Bellani, Cosimo Lacava, Ilaria Cristiani

Summary: In this work, we present the design of a silicon photonic-based polarization converting device integrating semiconductor InP nanowires on the silicon photonic platform. A comprehensive numerical analysis shows that the device can achieve full polarization conversion with minimal power loss in small footprints. This approach can pave the way for complex and reconfigurable photonic processors based on the manipulation of polarization state of guided light beams.

NANOMATERIALS (2022)

Article Chemistry, Multidisciplinary

Surface chemistry and structure manipulation of graphene-related materials to address the challenges of electrochemical energy storage

Yue Sun, Jinhua Sun, Jaime S. Sanchez, Zhenyuan Xia, Linhong Xiao, Ruiqi Chen, Vincenzo Palermo

Summary: Energy storage devices are essential for portable electronics, electric vehicles, and the electrical grid. Graphene has been recognized as a magic material due to its unique structure and excellent properties, making it valuable in addressing challenges in various energy storage systems. This feature article provides a comprehensive overview of strategies used in our research to develop graphene-based composite electrodes with improved performance compared to current electrodes.

CHEMICAL COMMUNICATIONS (2023)

Article Chemistry, Physical

Polarization Control in Integrated Graphene-Silicon Quantum Photonics Waveguides

Simone Cammarata, Andrea Fontana, Ali Emre Kaplan, Samuele Cornia, Thu Ha Dao, Cosimo Lacava, Valeria Demontis, Simone Iadanza, Valerio Vitali, Fabio De Matteis, Elena Pedreschi, Guido Magazzu, Alessandra Toncelli, Franco Spinella, Sergio Saponara, Roberto Gunnella, Francesco Rossella, Andrea Salamon, Vittorio Bellani

Summary: This study numerically investigates the use of graphene nanoribbons on silicon-on-insulator (SOI) strip waveguides for light polarization control in silicon photonic-integrated waveguides. The main factors affecting polarization control are found to be the graphene chemical potential and the waveguide's geometrical parameters.

MATERIALS (2022)

Article Engineering, Environmental

Amino acid-driven adsorption of emerging contaminants in water by modified graphene oxide nanosheets

Sebastiano Mantovani, Tainah Dorina Marforio, Sara Khaliha, Angela Pintus, Alessandro Kovtun, Francesca Tunioli, Laura Favaretto, Antonio Bianchi, Maria Luisa Navacchia, Vincenzo Palermo, Matteo Calvaresi, Manuela Melucci

Summary: In this study, graphene oxide nanosheets covalently modified with amino acids were synthesized and their adsorption properties toward a mixture of selected contaminants were investigated. The modified graphene oxide exhibited higher adsorption capacity for Bisphenol A, Benzophenone-4, and Carbamazepine compared to unmodified graphene oxide and reduced graphene oxide. Molecular dynamics simulations showed increased interaction energies between the modified graphene oxide and contaminants, which can be attributed to the presence of amino acid side chains on the nanosheet surface.

ENVIRONMENTAL SCIENCE-WATER RESEARCH & TECHNOLOGY (2023)

Article Biochemistry & Molecular Biology

New Random Aromatic/Aliphatic Copolymers of 2,5-Furandicarboxylic and Camphoric Acids with Tunable Mechanical Properties and Exceptional Gas Barrier Capability for Sustainable Mono-Layered Food Packaging

Giulia Guidotti, Michelina Soccio, Massimo Gazzano, Valentina Siracusa, Nadia Lotti

Summary: High molecular weight, fully biobased random copolymers of 2,5-furandicarboxylic acid (2,5-FDCA) containing different amounts of (1R, 3S)-(+)-Camphoric Acid (CA) were successfully synthesized and characterized. The addition of camphoric co-units led to modulation of the properties such as thermal, structural, mechanical, and barrier properties. The improved properties were associated with enhanced interchain interactions.

MOLECULES (2023)

Article Chemistry, Multidisciplinary

Mesoscopic 3D Charge Transport in Solution-Processed Graphene-Based Thin Films: A Multiscale Analysis

Alex Boschi, Alessandro Kovtun, Fabiola Liscio, Zhenyuan Xia, Kyung Ho Kim, Samuel Lara Avila, Sara De Simone, Valentina Mussi, Carlo Barone, Sergio Pagano, Marco Gobbi, Paolo Samori, Marco Affronte, Andrea Candini, Vincenzo Palermo, Andrea Liscio

Summary: Graphene and related 2D material (GRM) thin films consist of randomly distributed 3D assembly of 2D nanosheets interacting via van der Waals forces. The charge transport mechanisms in GRM thin films near the metal-insulator transition (MIT) are studied, with a focus on defect density and nanosheet arrangement. A general model is developed to describe the multiscale nature of charge transport in GRM thin films using two prototypical nanosheet types with different defect density and crystallinity.
Article Environmental Sciences

Influence of the Fabrication Conditions on the Physical Properties and Water Treatment Efficiency of Cellulose Acetate Porous Membranes

Rania E. Morsi, Franco Corticelli, Vittorio Morandi, Denis Gentili, Massimiliano Cavallini, Alberto Figoli, Francesca Russo, Francesco Galiano, Annalisa Aluigi, Barbara Ventura

Summary: In membrane-based water purification technology, the preparation conditions greatly affect the pore size distribution and dye removal efficiency of cellulose acetate membranes. Different fabrication methods and conditions, such as film casting speed, casted solution thickness, coagulation bath usage, and surfactant addition, significantly influence the membranes' pore size, porosity, and water permeability. The study also found that Azure A had better chemical affinity for cellulose acetate and was removed more efficiently, and both Azure A and Methyl Orange dye uptake followed a pseudo-second order model indicating chemisorption through valency forces.
Article Materials Science, Multidisciplinary

Thermoelectric and Structural Properties of Sputtered AZO Thin Films with Varying Al Doping Ratios

Muhammad Isram, Riccardo Magrin Maffei, Valeria Demontis, Leonardo Martini, Stiven Forti, Camilla Coletti, Vittorio Bellani, Andrea Mescola, Guido Paolicelli, Alberto Rota, Stefania Benedetti, Alessandro di Bona, Joana M. Ribeiro, Carlos J. Tavares, Francesco Rossella

Summary: Nanomaterials have the potential to revolutionize sustainable energy production by enabling highly efficient thermoelectric energy conversion and harvesting. This study focuses on a set of five Al:ZnO thin films with different Al doping levels, ranging from 2 to 8 at.%, to investigate their thermoelectric properties. The results show that the samples exhibited a Seebeck coefficient in the range of 22-33 mu V/K and a resistivity below 2 x 10(-3) Ohm center dot cm with a doping level of 3 at.%. These findings shed light on the potential applications of metal ZnO thin film technology in thermoelectric devices.

COATINGS (2023)

Article Chemistry, Physical

RuO2 Nanostructure as an Efficient and Versatile Catalyst for H2 Photosynthesis

Alberto Bianco, Alessandro Gradone, Vittorio Morandi, Giacomo Bergamini

Summary: Photocatalytic H-2 generation has great potential in the green production of alternative fuels and valuable chemicals. Commercial RuO2 nanostructures have been found to be a robust, versatile, and competitive catalyst for H-2 photoproduction. The catalyst's activities have been compared to those of platinum nanoparticle catalyst, showing a high hydrogen evolution rate and apparent quantum efficiency. The versatility and robustness of the system have been demonstrated in both water and organic media, with the catalyst being recoverable and reusable.

ACS APPLIED ENERGY MATERIALS (2023)

Article Nanoscience & Nanotechnology

Controllable Coating Graphene Oxide and Silanes on Cu Particles as Dual Protection for Anticorrosion

Jinhua Sun, Kristoffer Harr Martinsen, Uta Klement, Alessandro Kovtun, Zhenyuan Xia, Plinio Fernandes Borges Silva, Eduard Hryha, Lars Nyborg, Vincenzo Palermo

Summary: A reduced graphene oxide (RGO) coating strategy is developed to protect sintered Cu metal powders from corrosion by addressing the galvanic corrosion issue of graphene. A layer of silane molecules is deposited between the surface of Cu particles and the graphene oxide (GO), preventing direct contact and mitigating galvanic corrosion. The dual coating of GO and silane results in improved anticorrosion properties for Cu.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Engineering, Environmental

The removal efficiency of emerging organic contaminants, heavy metals and dyes: intrinsic limits at low concentrations

Sara Khaliha, Derek Jones, Alessandro Kovtun, Maria Luisa Navacchia, Massimo Zambianchi, Manuela Melucci, Vincenzo Palermo

Summary: In this study, we compared different materials in removing organic contaminants from water using Langmuir adsorption isotherms. We found that the removal efficiency reaches a limit at low concentrations and multi-step adsorption processes are more efficient than single-step adsorption with smaller amounts of adsorbent material. The concentration of the adsorbent strongly affects its performance. Furthermore, we emphasized the importance of reporting both Q(m) and K-L parameters for comparing materials tested under different experimental conditions in future work and reviews.

ENVIRONMENTAL SCIENCE-WATER RESEARCH & TECHNOLOGY (2023)

Article Materials Science, Multidisciplinary

Triboiontronics for efficient energy and information flow

Xiang Li, Shaoxin Li, Xin Guo, Jiajia Shao, Zhong Lin Wang, Di Wei

Summary: This paper introduces a novel method of dynamically regulating the electrical double layer through contact electrification, which allows for precise control of the polarity, quantity, and type of charges. This has potential applications in efficient energy harvesting and neuromorphic computing.

MATTER (2023)

Article Chemistry, Multidisciplinary

Facile high-yield synthesis and purification of lysine-modified graphene oxide for enhanced drinking water purification

Sebastiano Mantovani, Sara Khaliha, Tainah Dorina Marforio, Alessandro Kovtun, Laura Favaretto, Francesca Tunioli, Antonio Bianchi, Gaetana Petrone, Andrea Liscio, Vincenzo Palermo, Matteo Calvaresi, Maria Luisa Navacchia, Manuela Melucci

Summary: Lysine-covalently modified graphene oxide (GO-Lys) can enhance the adsorption capacity of bisphenol A, benzophenone-4, and carbamazepine contaminants from tap water, surpassing the state of the art.

CHEMICAL COMMUNICATIONS (2022)

Article Chemistry, Physical

Dendritic growth lowers carbon electrode work function for efficient perovskite solar cells

Jie Sheng, Jingshan He, Dun Ma, Yuanbo Wang, Wu Shao, Tian Ding, Ronghao Cen, Jingwen He, Zhihao Deng, Wenjun Wu

Summary: This study presents an innovative approach to improve the photovoltaic conversion characteristics and stability of perovskite solar cells through carbon electrode interface modification. By in-situ polymerization and carbonization on the surface of nano-graphite, a dendritic structure carbon electrode is formed, reducing the work function and aligning the energy levels with perovskite. This leads to improved charge and hole collection efficiency, resulting in increased photovoltaic conversion efficiency. Furthermore, the modified carbon electrode-based perovskite solar cells exhibit exceptional stability, maintaining high efficiency even without encapsulation.

CARBON (2024)

Article Chemistry, Physical

High-performance epoxy nanocomposites via constructing a rigid-flexible interface with graphene oxide functionalized by polyetheramine and f-SiO2

Guodong Shi, Jian Song, Xiaoxiao Tian, Tongtong Liu, Zhanjun Wu

Summary: This study demonstrates the improvement of mechanical properties and reduction of coefficient of thermal expansion (CTE) in graphene oxide (GO)/epoxy (EP) nanocomposites by enhancing the interface between GO and EP through functionalization and incorporating rigid-flexible interphases. The results reveal that the SiO2-PEA-GO hybrid exhibits better strengthening and toughening effects, as well as lower CTE, compared to the PEA-GO hybrid due to the presence of rigid-flexible interfaces with higher bonding strength and better energy dissipation mechanisms. Additionally, the nanocomposites with longer polyetheramine (PEA) molecules in the rigid-flexible interphases demonstrate higher strength and toughness, while maintaining a lower CTE. This work provides a promising strategy for constructing adjustable flexible-rigid interfacial structures and offers potential in developing GO/EP nanocomposites with high mechanical properties and low CTE.

CARBON (2024)

Article Chemistry, Physical

A facile route to the synthesis of carbon replicas cast from narrow-mesoporous matrices

Rafal Janus, Sebastian Jarczewski, Jacek Jagiello, Piotr Natkanski, Mariusz Wadrzyk, Marek Lewandowski, Marek Michalik, Piotr Kustrowski

Summary: In this study, a facile procedure for the synthesis of CMK-1 and CMK-2 carbon replicas was developed. The method utilizes basic laboratory equipment and a renewable carbon source, and operates under mild conditions. The resulting carbon mesostructures exhibit exquisite replication fidelity and structural homogeneity, making them suitable for applications in various fields.

CARBON (2024)

Article Chemistry, Physical

Microstructure and energetic characteristics of direct ink printed polymer-free rGO/nanothermite aerogel

Anqi Wang, Connor J. MacRobbie, Alex Baranovsky, Jean-Pierre Hickey, John Z. Wen

Summary: In this study, a novel polymer-free nanothermite aerogel with a wide range of nanoparticle loading was fabricated via a new additive manufacturing process. The SEM images showed a unique porous structure formed by extra thin rGO sheets, wrapping individual nanothermite clusters. The DSC-TGA results and high-speed combustion videos confirmed the enhanced energetic performance of the printed specimen.

CARBON (2024)

Article Chemistry, Physical

A solar-driven interfacial evaporator for seawater desalination based on mussel-inspired superhydrophobic composite coating

Wanze Wu, Misheng Zhao, Shiwei Miao, Xiaoyan Li, Yongzhong Wu, Xiao Gong, Hangxiang Wang

Summary: Superhydrophobic solar-driven interfacial evaporator is an energy-efficient technology for seawater desalination, which is easily fabricated using robust photothermal superhydrophobic coating and substrate. The created bifunctional coating on the melamine sponge substrate shows stable and highly efficient photothermal and superhydrophobic performance for seawater desalination. This superhydrophobic solar-driven interfacial evaporator is expected to have wide applications in seawater desalination.

CARBON (2024)

Article Chemistry, Physical

Bead-like flexible ZIF-67-derived Co@Carbon composite nanofibre mat for wideband microwave absorption in C-band

Zichen Xiang, Zhi Song, Tiansheng Wang, Menghang Feng, Yijing Zhao, Qitu Zhang, Yi Hou, Lixi Wang

Summary: This study presents a co-electrospinning synthesis strategy to fabricate lightweight and porous Co@C composite nanofibres with wideband microwave attenuation capacity. The addition of MOF-derived Co additives enhances the low-frequency absorption performance.

CARBON (2024)

Article Chemistry, Physical

A perovskite-graphene device for X-ray detection

J. Snow, C. Olson, E. Torres, K. Shirley, E. Cazalas

Summary: This study investigates the use of a perovskite-based graphene field effect transistor (P-GFET) device for X-ray detection. The sensitivity and responsivity of the device were found to be influenced by factors such as X-ray tube voltage, current, and source-drain voltage. Simulation experiments were conducted to determine the dose rate and energy incident on the device during irradiation.

CARBON (2024)

Article Chemistry, Physical

Microporous carbon prepared by microwave pyrolysis of scrap tyres and the effect of K+ in its structure on xylene adsorption

Zuzana Jankovska, Lenka Matejova, Jonas Tokarsky, Pavlina Peikertova, Milan Dopita, Karolina Gorzolkova, Dominika Habermannova, Michal Vastyl, Jakub Belik

Summary: This study provides new insights into microwave-assisted pyrolysis of scrap tyres, demonstrating that it can produce microporous carbon black with potential application in xylene adsorption. Compared to conventional pyrolysis, microwave pyrolysis requires less time and energy while maintaining similar adsorption capacity.

CARBON (2024)

Article Chemistry, Physical

Ambipolar charge transfer of larger fullerenes enabled by the modulated surface potential of h-BN/Rh(111)

Max Bommert, Bruno Schuler, Carlo A. Pignedoli, Roland Widmer, Oliver Groning

Summary: A detailed understanding of the interaction between molecules and two-dimensional materials is crucial for incorporating functional molecular films into next-generation 2D material-organic hybrid devices. This study compares the energy level alignment of different-sized fullerenes on a Moire superstructure and finds that C-84 fullerenes can be either neutral or negatively charged depending on slight variations of the electrostatic potential. This discovery suggests a new path to achieve ambipolar charge transfer without overcoming the electronic gap of fullerenes.

CARBON (2024)

Article Chemistry, Physical

Flexible SiO2/rGO aerogel for wide-angle broadband microwave absorption

Yuanjing Cheng, Xianxian Sun, Ye Yuan, Shuang Yang, Yuanhao Ning, Dan Wang, Weilong Yin, Yibin Li

Summary: The dual-structure aerogel (GS) consisting of flexible silica fibers and graphene honeycomb structures exhibits excellent resilience, flexibility, and reliability. It also shows remarkable wave absorbing performance, making it an ideal candidate for microwave absorption applications such as flexible electronics and aerospace.

CARBON (2024)

Article Chemistry, Physical

In situ self-adaptive growth of graphene coatings on hard substrates via competitive NiCo catalysis reaction

Shuyu Fan, Yinong Chen, Shu Xiao, Kejun Shi, Xinyu Meng, Songsheng Lin, Fenghua Su, Yifan Su, Paul K. Chu

Summary: Graphene coatings are promising solid lubrication materials due to their mechanical properties. This study presents a new method for in situ deposition of high-quality graphene coatings on hard substrates using NiCo solid solution and competitive reaction strategies. The graphene coating deposited on substrates with deep NiCo solid solution demonstrates superior low-friction and durability.

CARBON (2024)

Article Chemistry, Physical

Monodispersed semiconducting SWNTs significantly enhanced the thermoelectric performance of regioregular poly(3-dodecylthiophene) films

Mengdi Wang, Sanyin Qu, Yanling Chen, Qin Yao, Lidong Chen

Summary: The improved thermoelectric properties of conducting polymers are achieved by selectively capturing single-walled carbon nanotubes (SWNTs) in a conducting polymer film, leading to increased carrier mobility and reduced thermal conductivity. The resulting composite film exhibits significantly higher electrical conductivity and lower thermal conductivity compared to films with a mixture of SWNTs. This work provides a convenient and efficient method to enhance the thermoelectric properties of conducting polymers.

CARBON (2024)

Review Chemistry, Physical

Component optimization and microstructure design of carbon nanotube-based microwave absorbing materials: A review

Heng Wei, Weihua Li, Kareem Bachagha

Summary: This article reviews the research progress of carbon nanotube-based microwave absorbing materials (MAMs) in recent years, covering the fundamental theory, design strategies, synthesis methods, and future development directions.

CARBON (2024)

Article Chemistry, Physical

MXene-based polymer brushes decorated with small-sized Ag nanoparticles enabled high-performance lithium host for stable lithium metal battery

Chenguang Shi, Junlong Huang, Zongheng Cen, Tan Yi, Shaohong Liu, Ruowen Fu

Summary: This study developed a high-performance Li metal host material, which achieved dendrite-free Li deposition with a low nucleation overpotential and high Coulombic efficiencies through the combination of Ti3C2-g-PV4P sheets and Ag nanoparticles. The full cells assembled with the Li@host anode and LiFePO4 cathode exhibited high discharge capacity and excellent cycling stability, demonstrating a perspective design for future energy storage devices.

CARBON (2024)

Article Chemistry, Physical

A stable full cell having high energy density realized by using a three-dimensional current collector of carbon nanotubes and partial prelithiation of silicon monoxide

Tomotaro Mae, Kentaro Kaneko, Hiroki Sakurai, Suguru Noda

Summary: A new partial prelithiation method for SiO/C-CNT electrodes was developed, which showed reduced irreversible capacity and achieved high energy densities with good reversibility. The method allows for precise control of the degree of prelithiation and is applicable to various chemistries.

CARBON (2024)