4.7 Article

Construction of oxygen vacancy on Bi12O17C12 nanosheets by heat-treatment in H2O vapor for photocatalytic NO oxidation

期刊

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 123, 期 -, 页码 234-242

出版社

JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2022.02.018

关键词

Oxygen-vacancies; H2O vapor; Photocatalytic; NO oxidation; O-1(2)

资金

  1. National Natural Science Foundation of China [21703075, 51872107, 52073110,22002047]
  2. Natural Science Foundation of Hubei Province [2020CFB694, 2020CFB394]
  3. Fundamental Research Funds for the Central Universities [2662020LXPY005, 2662019QD018]

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In this study, oxygen vacancies (OVs) were introduced into C-doped Bi12O17C12 nanosheets by heat-treating in H2O vapor, leading to enhanced photocatalytic activity and molecular activation efficiency, as well as the generation of more reactive oxygen species.
Oxygen-vacancies (OVs) play significant roles in semiconductor-based photocatalysis, such as elevating light absorption property, photogenerated carries separation efficiency, molecular activation, and photocatalytic activity. However, heat-treatment of semiconductors in dangerous H-2 atmosphere is usually indispensable for OVs formation. In this work, C-doped Bi12O17C12 nanosheets were facially heat-treated in H2O vapor (similar to 2.3 vol%) mixed with Ar at 300 degrees C to in-situ introduce OVs by the proposed reactions of C(s) + H2O(g) -> CO(g) H-2(g) + O-Lattice -> H2O(g) + OV. The formation of OVs, which was confirmed by electron paramagnetic resonance (EPR), can narrow the band gap, and enhance the photogenerated e(-)/h(+) separation efficiency on Bi12O17C12. Moreover, OVs-rich Bi12O17C12 nanosheets can facilitate molecular O-2 activation and produce more reactive oxygen species (ROS), especially O-1(2), which greatly improve the NO to NO3- conversion efficiency with NO removal rate of similar to 63% and NO3- production selectivity of similar to 92.6 %. The present work will bring new insights into the construction and roles of OVs in semiconductor-based photocatalysis. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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