期刊
ADVANCED FUNCTIONAL MATERIALS
卷 26, 期 3, 页码 353-364出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201504048
关键词
-
类别
资金
- National Natural Science Foundation of China [21174012, 51221002, 21574009]
- Beijing Natural Science Foundation [2142026]
- Innovation and Promotion Project of Beijing University of Chemical Technology
An innovative approach for covalent-bond-activated mechanoresponse by complexing rhodamine or spiropyran with cyclodextrin (CD) is reported. This approach endows diverse fluorophores with perfect mechanochromism by introducing a supramolecular system. Unique characteristics such as noncovalent chemical modification and convenient preparation make this approach promising for practical applications. The strong hydrogen bonds provided by CD play a crucial role in triggering the mechanochromic switch. First, the hydrogen bonds seize both sides of the fluorophore's weak chemical bonds and tightly lock the fluorophore in the cavity of CD. Second, the hydrogen bonds prompt the aggregation of complex inclusions in large ordered arrays and strengthen the molecular interactions. In this way, the weak chemical bonds can focus more external force and stretch more easily upon shearing (quantified). This is the first report of supramolecule-triggered mechanochromic switches. This study opens an avenue to correlate a mechanochemical reaction with a supramolecular system.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据