4.7 Article

The influence of poorly-/well-dispersed organo-montmorillonite on interfacial compatibility, fire retardancy and smoke suppression of polypropylene/intumescent flame retardant composite system

期刊

JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 622, 期 -, 页码 367-377

出版社

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2022.04.101

关键词

Polymer-matrix composites (PMCs); Interfacial compatibility; Fire safety; Smoke toxicity; Mechanical performance

资金

  1. Natural Science Foundation of Fujian Province, China [2021 J05266]
  2. Talents Introduction Program of Xiamen University of Technology, China [YKJ19019R]
  3. Young and Middle-aged Teachers Educa-tion Scientific Research Project of Fujian Province [JAT190657]

向作者/读者索取更多资源

Flame retardant polypropylene/IFR/OMMT nanocomposites were prepared using melt intercalation technique, showing excellent flame retardancy, dripping resistance, and reduced smoke toxicity. This study provides an effective approach for fabricating high-performance polymeric materials.
A novel linear polymeric charring agent (PEPAPC) was synthesized via the nucleophilic substitution reaction, and then embedded into polypropylene (PP) substrate to improve the fire retardancy and antidripping performance. Unfortunately, the opposite polarity between intumescent flame retardant (IFR) and polymer-matrix could seriously deteriorate the interfacial compatibility, harmful to the flameretardant efficiency and smoke toxicity suppression of PP/IFR composites. For the foregoing reasons, flame retardant PP/IFR/Organo-montmorillonite (OMMT) nanocomposites with the combination of maleic anhydride-grafted PP as compatibilizer have been prepared via melt intercalation technique. When 2 wt% well-dispersed OMMT were incorporated, it showed a significant reduction in peak heat release rate and total heat release (90.5 and 62.7%) compared with pristine PP, and an achievement in limiting oxygen index value of 32% from 18.5% for pristine PP, which can be attributed to the nanobarrier and catalytic carbonization effect of well-dispersed OMMT within the polymer-matrix. More importantly, the well-dispersed OMMT displays significant smoke toxicity suppression, toughening and strengthening effect on PP/IFR system. The peak CO release and total smoke production for PP-6 were decreased by 89.8 and 64.7%, respectively. This work may provide an effective approach towards fabricating high-performance polymeric materials on organic/inorganic hybrid nanocomposites with homogenous dispersion, thereby effectively reducing the fire hazard risk. (c) 2022 Elsevier Inc. All rights reserved.

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